Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

Nadia Marino; Susan K. Hanson; Peter Müller; Robert P. Doyle

doi:10.1021/ic3015767

Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

Nadia Marino, Susan K. Hanson, Peter Müller, Robert P. Doyle

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10 Scopus citations

Abstract

The complex {[ (V ^IVO)bipy(H ₂O)] ₂(μ- P ₂O ₇)}3H ₂O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.

Original language	English (US)
Pages (from-to)	10077-10079
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	19
DOIs	https://doi.org/10.1021/ic3015767
State	Published - Oct 1 2012

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex",

abstract = "The complex {[ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)}3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.",

author = "Nadia Marino and Hanson, {Susan K.} and Peter M{\"u}ller and Doyle, {Robert P.}",

year = "2012",

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language = "English (US)",

volume = "51",

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journal = "Inorganic Chemistry",

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T1 - Pyro without fire

T2 - Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

AU - Marino, Nadia

AU - Hanson, Susan K.

AU - Müller, Peter

AU - Doyle, Robert P.

PY - 2012/10/1

Y1 - 2012/10/1

N2 - The complex {[ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)}3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.

AB - The complex {[ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)}3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

Abstract

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