Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

Nadia Marino, Susan K. Hanson, Peter Müller, Robert P. Doyle

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

The complex {[ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)}3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.

Original languageEnglish (US)
Pages (from-to)10077-10079
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number19
DOIs
StatePublished - Oct 1 2012

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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