Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex

Nadia Marino, Susan K. Hanson, Peter Müller, Robert Patrick Doyle

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The complex {[ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)}3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.

Original languageEnglish (US)
Pages (from-to)10077-10079
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number19
DOIs
StatePublished - Oct 1 2012

Fingerprint

Benzyl Alcohol
Nanocrystalline powders
Vanadates
Coordination Complexes
catalytic activity
Catalyst activity
Fires
alcohols
reactivity
Single crystals
Oxidation
oxidation
air
single crystals
Testing
room temperature
synthesis
Air
Temperature
diphosphoric acid

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Pyro without fire : Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex. / Marino, Nadia; Hanson, Susan K.; Müller, Peter; Doyle, Robert Patrick.

In: Inorganic Chemistry, Vol. 51, No. 19, 01.10.2012, p. 10077-10079.

Research output: Contribution to journalArticle

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