Preparation and X-ray crystal structure of [S2MoS2Mo(NNMe2)2(PPh3)], a binuclear molybdenum hydrazido(2–)-complex containing co-ordinated tetrathiomolybdate

Jonathan R. Dilworth, Jon A. Zubieta

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

Reaction of [MCl(NNMe2)2(PPh3)2]Cl (M = Mo or W) with [Bun4N]2[M'S4] (M' = Mo, W) gives the complexes [S2M'S2M(NNMe2)2(PPh3)]; an X-ray crystal structure of the dinuclear complex with M = M' = Mo shows the molybdenum atoms to have distorted tetrahedral and trigonal bipyramidal geometries.

Original languageEnglish (US)
Pages (from-to)132-133
Number of pages2
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number3
DOIs
StatePublished - Jan 1 1981
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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