Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes

J. Hyde, Jon A Zubieta

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.

Original languageEnglish (US)
Pages (from-to)289-296
Number of pages8
JournalJournal of Inorganic and Nuclear Chemistry
Volume39
Issue number2
DOIs
StatePublished - 1977
Externally publishedYes

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Molybdenum
Electrolysis
molybdenum
Paramagnetic resonance
Nuclear magnetic resonance
isopropyl compounds
electronic spectra
preparation
electrolysis
analogs
nuclear magnetic resonance
oligomycin sensitivity-conferring protein

Cite this

Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes. / Hyde, J.; Zubieta, Jon A.

In: Journal of Inorganic and Nuclear Chemistry, Vol. 39, No. 2, 1977, p. 289-296.

Research output: Contribution to journalArticle

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