Abstract
Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 289-296 |
| Number of pages | 8 |
| Journal | Journal of Inorganic and Nuclear Chemistry |
| Volume | 39 |
| Issue number | 2 |
| DOIs | |
| State | Published - 1977 |
| Externally published | Yes |
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Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes. / Hyde, J.; Zubieta, Jon A.
In: Journal of Inorganic and Nuclear Chemistry, Vol. 39, No. 2, 1977, p. 289-296.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes
AU - Hyde, J.
AU - Zubieta, Jon A
PY - 1977
Y1 - 1977
N2 - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.
AB - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.
UR - http://www.scopus.com/inward/record.url?scp=15844428328&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=15844428328&partnerID=8YFLogxK
U2 - 10.1016/0022-1902(77)80016-X
DO - 10.1016/0022-1902(77)80016-X
M3 - Article
VL - 39
SP - 289
EP - 296
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 2
ER -