TY - JOUR
T1 - Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes
AU - Hyde, J.
AU - Zubieta, Jon
N1 - Funding Information:
Acknowledgements--We are indebted to the Research Foundation of the State University of New York for partial support of this research, to Mr. J. Mazursky for repeating many of the preparations, to the National Science Foundation for a grant to J M. under the Undergraduate Research Program Grant EPP75-04025, to Dr. A. Nieupoort of the University of Nijmegen for a copy of his thesis and particularly to Dr. K. Willemse of lhe University of Nijmegen for stimulating discussions and for providing us with references on related chemical species• Support by the National Institutes of Health (Grant No. GM22566-01) is gratefully acknowledged.
PY - 1977
Y1 - 1977
N2 - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.
AB - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.
UR - http://www.scopus.com/inward/record.url?scp=15844428328&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=15844428328&partnerID=8YFLogxK
U2 - 10.1016/0022-1902(77)80016-X
DO - 10.1016/0022-1902(77)80016-X
M3 - Article
AN - SCOPUS:15844428328
VL - 39
SP - 289
EP - 296
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 2
ER -