Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes

J. Hyde; Jon Zubieta

doi:10.1016/0022-1902(77)80016-X

Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes

J. Hyde, Jon Zubieta

Research output: Contribution to journal › Article

25 Scopus citations

Abstract

Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S₂CSiC₃H₇)₄, at +0.4 V yields [Mo(S₂CSiC₃H₇)₄]⁺. The ESR and electronic spectra of this Mo(V) complex are discussed.

Original language	English (US)
Pages (from-to)	289-296
Number of pages	8
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	39
Issue number	2
DOIs	https://doi.org/10.1016/0022-1902(77)80016-X
State	Published - 1977
Externally published	Yes

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Hyde, J., & Zubieta, J. (1977). Preparation and characterization of tetrakis(thioxanthato)molybdenum(IV) complexes. Journal of Inorganic and Nuclear Chemistry, 39(2), 289-296. https://doi.org/10.1016/0022-1902(77)80016-X

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abstract = "Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.",

author = "J. Hyde and Jon Zubieta",

year = "1977",

doi = "10.1016/0022-1902(77)80016-X",

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AU - Hyde, J.

AU - Zubieta, Jon

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N2 - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.

AB - Several thixanthato complexes of Mo(IV) have been prepared and characterized as diamagnetic, 8-coordinate species. The IR, NMR and electronic spectra of these complexes are discussed and compared with the previously reported dithiocarbamate and dithiocarboxylate analogues. The complexes are electrochemically active, and controlled potential electrolysis of the isopropyl compound, Mo(S2CSiC3H7)4, at +0.4 V yields [Mo(S2CSiC3H7)4]+. The ESR and electronic spectra of this Mo(V) complex are discussed.

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10.1016/0022-1902(77)80016-X