Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B18H22 borane cluster: Crystal structure of [(CH3)4N][anti-B18H20Co(CO)3 ]

Jesse W. Taylor; Ulrich Englich; Karin Ruhlandt-Senge; James T. Spencer

doi:10.1021/om020139d

Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B₁₈H₂₂ borane cluster: Crystal structure of [(CH₃)₄N][anti-B₁₈H₂₀Co(CO)₃]

Jesse W. Taylor, Ulrich Englich, Karin Ruhlandt-Senge, James T. Spencer

Research output: Contribution to journal › Article › peer-review

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Abstract

The preparation of macropolyhedral metallaborane clusters from the anti-B₁₈H₂₂ Borane cluster was discussed. The reaction of anti-B₁₈H₂₂ with [Co₂(CO)₈] and [η⁵-C₅H₅)Fe(CO)₂(C₆H₁₀)]⁺ yields the macropolyhedral metallaboranes [anti-B₁₈H₂₀Co(CO)₃][(CH₃)₄N] (1) and [9-(Fe(CO)₂(η⁵-C₅H₅))-anti- B₁₈H₂₁]. Single crystal x-ray diffraction analysis of complex (1) showed that the structure consists of an 11-vertex nido-cobaltaborane subunit edge shared with a 10-vertex nido-borane fragment.

Original language	English (US)
Pages (from-to)	3054-3057
Number of pages	4
Journal	Organometallics
Volume	21
Issue number	14
DOIs	https://doi.org/10.1021/om020139d
State	Published - Jul 8 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B18H22 borane cluster: Crystal structure of [(CH3)4N][anti-B18H20Co(CO)3 ]",

abstract = "The preparation of macropolyhedral metallaborane clusters from the anti-B18H22 Borane cluster was discussed. The reaction of anti-B18H22 with [Co2(CO)8] and [η5-C5H5)Fe(CO)2(C6 H10)]+ yields the macropolyhedral metallaboranes [anti-B18H20Co(CO)3][(CH3) 4N] (1) and [9-(Fe(CO)2(η5-C5H5))-anti- B18H21]. Single crystal x-ray diffraction analysis of complex (1) showed that the structure consists of an 11-vertex nido-cobaltaborane subunit edge shared with a 10-vertex nido-borane fragment.",

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T1 - Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B18H22 borane cluster

T2 - Crystal structure of [(CH3)4N][anti-B18H20Co(CO)3 ]

AU - Taylor, Jesse W.

AU - Englich, Ulrich

AU - Ruhlandt-Senge, Karin

AU - Spencer, James T.

PY - 2002/7/8

Y1 - 2002/7/8

N2 - The preparation of macropolyhedral metallaborane clusters from the anti-B18H22 Borane cluster was discussed. The reaction of anti-B18H22 with [Co2(CO)8] and [η5-C5H5)Fe(CO)2(C6 H10)]+ yields the macropolyhedral metallaboranes [anti-B18H20Co(CO)3][(CH3) 4N] (1) and [9-(Fe(CO)2(η5-C5H5))-anti- B18H21]. Single crystal x-ray diffraction analysis of complex (1) showed that the structure consists of an 11-vertex nido-cobaltaborane subunit edge shared with a 10-vertex nido-borane fragment.

AB - The preparation of macropolyhedral metallaborane clusters from the anti-B18H22 Borane cluster was discussed. The reaction of anti-B18H22 with [Co2(CO)8] and [η5-C5H5)Fe(CO)2(C6 H10)]+ yields the macropolyhedral metallaboranes [anti-B18H20Co(CO)3][(CH3) 4N] (1) and [9-(Fe(CO)2(η5-C5H5))-anti- B18H21]. Single crystal x-ray diffraction analysis of complex (1) showed that the structure consists of an 11-vertex nido-cobaltaborane subunit edge shared with a 10-vertex nido-borane fragment.

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Preparation and characterization of macropolyhedral metallaborane clusters from the anti-B₁₈H₂₂ borane cluster: Crystal structure of [(CH₃)₄N][anti-B₁₈H₂₀Co(CO)₃]

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