TY - JOUR
T1 - Polyoxovanadium–Organophosphonates—Properties and Structure of an Unusual Pentavanadate Species with a VO Group Directed Toward the Interior of the Molecular Cavity
AU - Chen, Qin
AU - Zubieta, Jon
PY - 1993/2
Y1 - 1993/2
N2 - An unsymmetrical bowllike [V3O5(PhPO3)4] framework (V2–V4, P1–P4), on whose surface a VO unit (V1) is “condensed”, and which is capped by octahedrally coordinated V atom (V5), is formed by the anion of 1 · CH3OH. A terminal oxo group (O23) is encapsulated in this cavity (phenyl substituents at P1, P3, P4 are omitted from the structure shown right). (Figure Presented.) (Formula Presented.)
AB - An unsymmetrical bowllike [V3O5(PhPO3)4] framework (V2–V4, P1–P4), on whose surface a VO unit (V1) is “condensed”, and which is capped by octahedrally coordinated V atom (V5), is formed by the anion of 1 · CH3OH. A terminal oxo group (O23) is encapsulated in this cavity (phenyl substituents at P1, P3, P4 are omitted from the structure shown right). (Figure Presented.) (Formula Presented.)
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U2 - 10.1002/anie.199302611
DO - 10.1002/anie.199302611
M3 - Article
AN - SCOPUS:33748237073
SN - 0570-0833
VL - 32
SP - 261
EP - 263
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 2
ER -