Polyoxovanadium–Organophosphonates—Properties and Structure of an Unusual Pentavanadate Species with a VO Group Directed Toward the Interior of the Molecular Cavity

Qin Chen, Jon Zubieta

Research output: Contribution to journalArticle

33 Scopus citations

Abstract

An unsymmetrical bowllike [V3O5(PhPO3)4] framework (V2–V4, P1–P4), on whose surface a VO unit (V1) is “condensed”, and which is capped by octahedrally coordinated V atom (V5), is formed by the anion of 1 · CH3OH. A terminal oxo group (O23) is encapsulated in this cavity (phenyl substituents at P1, P3, P4 are omitted from the structure shown right). (Figure Presented.) (Formula Presented.)

Original languageEnglish (US)
Pages (from-to)261-263
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume32
Issue number2
DOIs
StatePublished - Feb 1993

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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