Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C4H9)4N]2[Mo2O5(eryth)] and [(n-C4H9)4N][Mo2O5(Heryth)]

Lidun Ma; Shuncheng Liu; Jon Zubieta

doi:10.1016/S0277-5387(00)80337-X

Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C₄H₉)₄N]₂[Mo₂O₅(eryth)] and [(n-C₄H₉)₄N][Mo₂O₅(Heryth)]

Lidun Ma, Shuncheng Liu, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

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Abstract

The reaction of [(n-C₄H₉)₄N]₂[MO₂O₇] with meso-erythritol in methanol yields [(n-C₄H₉)₄N]₂[Mo₂O₅(eryth)]·0.5C₄H₁₀O₄·H₂O (I), a complex having the [Mo₂O₅]²⁺ core bound to a single erythritolate tetraanion. Reaction of I with chloroacetic acid in methanol results in a single protonation of the coordinated erythritolate ligand to give [(n-C₄H₉)₄N][Mo₂O₅(Heryth)] (II). Crystal data: C₄₀H₈₅N₂O₁₂Mo₂ (I): orthorhombic, space group Pbca, a = 16.651(3), b = 24.043(5), c = 24.935(5) Å, V = 9982.5(12) Å³, Z = 8, D_calc = 1.30 g cm^-3; 3625 reflections to give R = 0.0522. C₂₀H₄₃NO₉Mo₂ (II): monoclinic, space group P2₁/n, a = 21.827(4), b = 18.638(3), c = 29.188(4) Å, β = 108.3(1)°, V= 11269.9(15) Å³, Z = 16, D_calc = 1.49 g cm^-3; 5911 reflections to give R = 0.0687.

Original language	English (US)
Pages (from-to)	1571-1573
Number of pages	3
Journal	Polyhedron
Volume	8
Issue number	12
DOIs	https://doi.org/10.1016/S0277-5387(00)80337-X
State	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(00)80337-X

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@article{b860f1d737474600846986814efe8b9e,

title = "Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C4H9)4N]2[Mo2O5(eryth)] and [(n-C4H9)4N][Mo2O5(Heryth)]",

abstract = "The reaction of [(n-C4H9)4N]2[MO2O7] with meso-erythritol in methanol yields [(n-C4H9)4N]2[Mo2O5(eryth)]·0.5C4H10O4·H2O (I), a complex having the [Mo2O5]2+ core bound to a single erythritolate tetraanion. Reaction of I with chloroacetic acid in methanol results in a single protonation of the coordinated erythritolate ligand to give [(n-C4H9)4N][Mo2O5(Heryth)] (II). Crystal data: C40H85N2O12Mo2 (I): orthorhombic, space group Pbca, a = 16.651(3), b = 24.043(5), c = 24.935(5) {\AA}, V = 9982.5(12) {\AA}3, Z = 8, Dcalc = 1.30 g cm-3; 3625 reflections to give R = 0.0522. C20H43NO9Mo2 (II): monoclinic, space group P21/n, a = 21.827(4), b = 18.638(3), c = 29.188(4) {\AA}, β = 108.3(1)°, V= 11269.9(15) {\AA}3, Z = 16, Dcalc = 1.49 g cm-3; 5911 reflections to give R = 0.0687.",

author = "Lidun Ma and Shuncheng Liu and Jon Zubieta",

year = "1989",

doi = "10.1016/S0277-5387(00)80337-X",

language = "English (US)",

volume = "8",

pages = "1571--1573",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "12",

}

TY - JOUR

T1 - Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C4H9)4N]2[Mo2O5(eryth)] and [(n-C4H9)4N][Mo2O5(Heryth)]

AU - Ma, Lidun

AU - Liu, Shuncheng

AU - Zubieta, Jon

PY - 1989

Y1 - 1989

N2 - The reaction of [(n-C4H9)4N]2[MO2O7] with meso-erythritol in methanol yields [(n-C4H9)4N]2[Mo2O5(eryth)]·0.5C4H10O4·H2O (I), a complex having the [Mo2O5]2+ core bound to a single erythritolate tetraanion. Reaction of I with chloroacetic acid in methanol results in a single protonation of the coordinated erythritolate ligand to give [(n-C4H9)4N][Mo2O5(Heryth)] (II). Crystal data: C40H85N2O12Mo2 (I): orthorhombic, space group Pbca, a = 16.651(3), b = 24.043(5), c = 24.935(5) Å, V = 9982.5(12) Å3, Z = 8, Dcalc = 1.30 g cm-3; 3625 reflections to give R = 0.0522. C20H43NO9Mo2 (II): monoclinic, space group P21/n, a = 21.827(4), b = 18.638(3), c = 29.188(4) Å, β = 108.3(1)°, V= 11269.9(15) Å3, Z = 16, Dcalc = 1.49 g cm-3; 5911 reflections to give R = 0.0687.

AB - The reaction of [(n-C4H9)4N]2[MO2O7] with meso-erythritol in methanol yields [(n-C4H9)4N]2[Mo2O5(eryth)]·0.5C4H10O4·H2O (I), a complex having the [Mo2O5]2+ core bound to a single erythritolate tetraanion. Reaction of I with chloroacetic acid in methanol results in a single protonation of the coordinated erythritolate ligand to give [(n-C4H9)4N][Mo2O5(Heryth)] (II). Crystal data: C40H85N2O12Mo2 (I): orthorhombic, space group Pbca, a = 16.651(3), b = 24.043(5), c = 24.935(5) Å, V = 9982.5(12) Å3, Z = 8, Dcalc = 1.30 g cm-3; 3625 reflections to give R = 0.0522. C20H43NO9Mo2 (II): monoclinic, space group P21/n, a = 21.827(4), b = 18.638(3), c = 29.188(4) Å, β = 108.3(1)°, V= 11269.9(15) Å3, Z = 16, Dcalc = 1.49 g cm-3; 5911 reflections to give R = 0.0687.

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U2 - 10.1016/S0277-5387(00)80337-X

DO - 10.1016/S0277-5387(00)80337-X

M3 - Article

AN - SCOPUS:0001721528

SN - 0277-5387

VL - 8

SP - 1571

EP - 1573

JO - Polyhedron

JF - Polyhedron

IS - 12

ER -

Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C₄H₉)₄N]₂[Mo₂O₅(eryth)] and [(n-C₄H₉)₄N][Mo₂O₅(Heryth)]

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