Polyoxo Alkoxide Clusters of Vanadium: Structural Characterization of the Decavanadate Core in the “Fully Reduced” Vanadium(IV) Species [V10O16{(OCH2)3CCH2CH3}4]4− and [V10O16(OH)2{(OCH)2)3CCH2OH}4]2− and in the Mixed-Valence Clusters [VIV8VV2O16{(OCH2)3CR}4]2− (R = -CH2CH3, -CH3)

M. Ishaque Khan, Qin Chen, D. P. Goshorn, Jon Zubieta

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Dive into the research topics of 'Polyoxo Alkoxide Clusters of Vanadium: Structural Characterization of the Decavanadate Core in the “Fully Reduced” Vanadium(IV) Species [V<sub>10</sub>O<sub>16</sub>{(OCH<sub>2</sub>)<sub>3</sub>CCH<sub>2</sub>CH<sub>3</sub>}<sub>4</sub>]<sup>4−</sup> and [V<sub>10</sub>O<sub>16</sub>(OH)<sub>2</sub>{(OCH)<sub>2</sub>)<sub>3</sub>CCH<sub>2</sub>OH}<sub>4</sub>]<sup>2−</sup> and in the Mixed-Valence Clusters [V<sup>IV</sup><sub>8</sub>V<sup>V</sup><sub>2</sub>O<sub>16</sub>{(OCH<sub>2</sub>)<sub>3</sub>CR}<sub>4</sub>]<sup>2−</sup> (R = -CH<sub>2</sub>CH<sub>3</sub>, -CH<sub>3</sub>)'. Together they form a unique fingerprint.

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