Polymerization of acetylene with a ruthenium olefin metathesis catalyst

Danielle E. Schuehler; Joseph E. Williams; Michael B. Sponsler

doi:10.1021/ma048694+

Polymerization of acetylene with a ruthenium olefin metathesis catalyst

Danielle E. Schuehler, Joseph E. Williams, Michael B. Sponsler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The ring opening polymerization of polyacetylene (PA) along with ruthenium olefin metathesis catalyst, was analyzed. The coatings of PA on glass plates were obtained by inserting the substrate in a solution of catalyst under acetylene, by varying exposure times, loose and porous films of various thicknesses were deposited. Shiny, silver-coated films were also obtained by using high pressure, moderate pressure, or low pressure. The scanning electron microscope (SEM) images of PA revealed that morphology is network of spherical particles near 0.5 μm in diameter.

Original language	English (US)
Pages (from-to)	6255-6257
Number of pages	3
Journal	Macromolecules
Volume	37
Issue number	17
DOIs	https://doi.org/10.1021/ma048694+
State	Published - Aug 24 2004

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "The ring opening polymerization of polyacetylene (PA) along with ruthenium olefin metathesis catalyst, was analyzed. The coatings of PA on glass plates were obtained by inserting the substrate in a solution of catalyst under acetylene, by varying exposure times, loose and porous films of various thicknesses were deposited. Shiny, silver-coated films were also obtained by using high pressure, moderate pressure, or low pressure. The scanning electron microscope (SEM) images of PA revealed that morphology is network of spherical particles near 0.5 μm in diameter.",

author = "Schuehler, {Danielle E.} and Williams, {Joseph E.} and Sponsler, {Michael B.}",

year = "2004",

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AU - Schuehler, Danielle E.

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AU - Sponsler, Michael B.

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N2 - The ring opening polymerization of polyacetylene (PA) along with ruthenium olefin metathesis catalyst, was analyzed. The coatings of PA on glass plates were obtained by inserting the substrate in a solution of catalyst under acetylene, by varying exposure times, loose and porous films of various thicknesses were deposited. Shiny, silver-coated films were also obtained by using high pressure, moderate pressure, or low pressure. The scanning electron microscope (SEM) images of PA revealed that morphology is network of spherical particles near 0.5 μm in diameter.

AB - The ring opening polymerization of polyacetylene (PA) along with ruthenium olefin metathesis catalyst, was analyzed. The coatings of PA on glass plates were obtained by inserting the substrate in a solution of catalyst under acetylene, by varying exposure times, loose and porous films of various thicknesses were deposited. Shiny, silver-coated films were also obtained by using high pressure, moderate pressure, or low pressure. The scanning electron microscope (SEM) images of PA revealed that morphology is network of spherical particles near 0.5 μm in diameter.

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ER -

Polymerization of acetylene with a ruthenium olefin metathesis catalyst

Abstract

ASJC Scopus subject areas

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