Plating and Stripping Calcium at Room Temperature in an Ionic-Liquid Electrolyte

Saeid Biria, Shreyas Pathreeker, Francielli S. Genier, Hansheng Li, Ian D. Hosein

Research output: Contribution to journalArticle

Abstract

Calcium batteries are an emerging, next generation energy storage technology undergoing intense research toward viable operation. A key aspect in their development is plating and stripping of a calcium metal anode in suitable electrolytes. Herein, we report that calcium can be plated and stripped at room temperature in an ionic-liquid-based electrolyte. Thick continuous deposits (∼20 μm) of crystalline calcium are plated and stripped over 10 cycles to areal capacities of 2.2 mAh cm-2 at a current density of 0.56 mA/cm2. This work presents ionic liquids as viable electrolytes for calcium anodes to enable redox activity for calcium batteries.

Original languageEnglish (US)
Pages (from-to)2310-2314
Number of pages5
JournalACS Applied Energy Materials
Volume3
Issue number3
DOIs
StatePublished - Mar 23 2020

Keywords

  • anode
  • calcium batteries
  • energy storage
  • ionic liquid
  • multivalent
  • plating
  • stripping

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrochemistry
  • Materials Chemistry
  • Electrical and Electronic Engineering

Fingerprint Dive into the research topics of 'Plating and Stripping Calcium at Room Temperature in an Ionic-Liquid Electrolyte'. Together they form a unique fingerprint.

  • Cite this