Photoredox laser chemistry of transition metal oxides

J. M. Osman, R. J. Bussjager, F. Nash, J. Chaiken, R. M. Villarica

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

We describe two-color laser excitation of tungsten oxide in ambient air to effect a fully reversible photoredox cycle. One color is infrared, apparently functioning as heat, and the other is visible or shorter wavelength, but not necessarily super bandgap, apparently supplying electronic excitation. In the case of either tungsten oxide or molybdenum oxide, the process can be monitored using a very strong set of Raman spectroscopic features. This process could find application in optical data storage and may be a generally useful strategy for manipulating transition metal oxides.

Original languageEnglish (US)
Pages (from-to)223-228
Number of pages6
JournalApplied Physics A: Materials Science and Processing
Volume66
Issue number2
DOIs
StatePublished - Jan 1 1998

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

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