Phonon Kinetics of Fructose at the Melting Transition

Alex Davie, Farah Vandrevala, Sara Dampf, Yanting Deng, Deepu K. George, Eric D. Sylvester, Timothy Korter, Erik Einarsson, Jason B. Benedict, Andrea G. Markelz

Research output: Contribution to journalArticlepeer-review

1 Scopus citations


Terahertz time domain spectroscopy (THz TDS) is used to measure the melting kinetics of fructose molecular crystals. Combining single-crystal anisotropy measurements with density functional calculations, we assign the phonon frequencies and interrogate how specific phonons behave with melting. While nearly all the low-frequency phonons continuously red-shift with heating and melting, the lowest-energy phonon polarized along thec-axis blue-shifts at the melting temperature, suggesting an initial structural change immediately before melting. We find that the kinetics follow a 3D growth model with large activation energies, consistent with previous differential scanning calorimetry (DSC) measurements. The large activation energies indicate that multiple H-bonds must break collectively for the transition. The results suggest the generality of the kinetics for molecular crystals and that THz TDS with picosecond resolution could be used to measure ultrafast kinetics.

Original languageEnglish (US)
Pages (from-to)12269-12276
Number of pages8
JournalJournal of Physical Chemistry C
Issue number22
StatePublished - Jun 10 2021

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Energy
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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