(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the VV Cluster [V10O24(O3AsC6H4‐4‐NH2)3]4− and the VIV/VVCluster [H2{V6O10(O3AsC6H5)6}]2−

M. Ishaque Khan, Yuanda Chang, Qin Chen, Hakon Hope, Sean Parking, D. P. Goshorn, Jon Zubieta

Research output: Contribution to journalArticle

37 Scopus citations

Abstract

Three {V3O13} units linked to form a ring that encloses the central V atom are found in the VV title compound. The VIV/VV cluster consists of a layered structure composed of three {V2As2O4} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the VV compound is shown on the right. • = V. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1197-1200
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume31
Issue number9
DOIs
StatePublished - Sep 1992

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of '(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V<sup>V</sup> Cluster [V<sub>10</sub>O<sub>24</sub>(O<sub>3</sub>AsC<sub>6</sub>H<sub>4</sub>‐4‐NH<sub>2</sub>)<sub>3</sub>]<sup>4−</sup> and the V<sup>IV</sup>/V<sup>V</sup>Cluster [H<sub>2</sub>{V<sub>6</sub>O<sub>10</sub>(O<sub>3</sub>AsC<sub>6</sub>H<sub>5</sub>)<sub>6</sub>}]<sup>2−</sup>'. Together they form a unique fingerprint.

  • Cite this