(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the VV Cluster [V10O24(O3AsC6H4‐4‐NH2)3]4− and the VIV/VVCluster [H2{V6O10(O3AsC6H5)6}]2−

M. Ishaque Khan; Yuanda Chang; Qin Chen; Hakon Hope; Sean Parking; D. P. Goshorn; Jon Zubieta

doi:10.1002/anie.199211971

(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V^V Cluster [V₁₀O₂₄(O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ and the V^IV/V^VCluster [H₂{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻

M. Ishaque Khan, Yuanda Chang, Qin Chen, Hakon Hope, Sean Parking, D. P. Goshorn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Three {V₃O₁₃} units linked to form a ring that encloses the central V atom are found in the V^V title compound. The V^IV/V^V cluster consists of a layered structure composed of three {V₂As₂O₄} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the V^V compound is shown on the right. • = V. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1197-1200
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	9
DOIs	https://doi.org/10.1002/anie.199211971
State	Published - Sep 1992

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199211971

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Khan, M. I., Chang, Y., Chen, Q., Hope, H., Parking, S., Goshorn, D. P., & Zubieta, J. (1992). (Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V^V Cluster [V₁₀O₂₄(O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ and the V^IV/V^VCluster [H₂{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻. Angewandte Chemie International Edition in English, 31(9), 1197-1200. https://doi.org/10.1002/anie.199211971

(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V^V Cluster [V₁₀O₂₄(O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ and the V^IV/V^VCluster [H₂{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻. / Khan, M. Ishaque; Chang, Yuanda; Chen, Qin et al.
In: Angewandte Chemie International Edition in English, Vol. 31, No. 9, 09.1992, p. 1197-1200.

Research output: Contribution to journal › Article › peer-review

Khan, MI, Chang, Y, Chen, Q, Hope, H, Parking, S, Goshorn, DP & Zubieta, J 1992, '(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V^V Cluster [V₁₀O₂₄(O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ and the V^IV/V^VCluster [H₂{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻', Angewandte Chemie International Edition in English, vol. 31, no. 9, pp. 1197-1200. https://doi.org/10.1002/anie.199211971

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title = "(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the VV Cluster [V10O24(O3AsC6H4‐4‐NH2)3]4− and the VIV/VVCluster [H2{V6O10(O3AsC6H5)6}]2−",

abstract = "Three {V3O13} units linked to form a ring that encloses the central V atom are found in the VV title compound. The VIV/VV cluster consists of a layered structure composed of three {V2As2O4} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the VV compound is shown on the right. • = V. (Figure Presented.)",

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T2 - Properties and Structures of the VV Cluster [V10O24(O3AsC6H4‐4‐NH2)3]4− and the VIV/VVCluster [H2{V6O10(O3AsC6H5)6}]2−

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AU - Chang, Yuanda

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AU - Hope, Hakon

AU - Parking, Sean

AU - Goshorn, D. P.

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N2 - Three {V3O13} units linked to form a ring that encloses the central V atom are found in the VV title compound. The VIV/VV cluster consists of a layered structure composed of three {V2As2O4} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the VV compound is shown on the right. • = V. (Figure Presented.)

AB - Three {V3O13} units linked to form a ring that encloses the central V atom are found in the VV title compound. The VIV/VV cluster consists of a layered structure composed of three {V2As2O4} rings. These are further examples of the exotic structures which are par for polyoxometalates. They show the profound influence that even a subtle change in the organic ligand can exert on the structure. The structure of the VV compound is shown on the right. • = V. (Figure Presented.)

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(Organoarsonato)polyoxovanadium Clusters: Properties and Structures of the V^V Cluster [V₁₀O₂₄(O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ and the V^IV/V^VCluster [H₂{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻

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