Organic-inorganic hybrid materials: Ligand influences on the structural chemistry of copper-vanadates

Paul Deburgomaster; Jon Zubieta

doi:10.1016/j.ica.2010.03.036

Organic-inorganic hybrid materials: Ligand influences on the structural chemistry of copper-vanadates

Paul Deburgomaster, Jon Zubieta

Department of Chemistry

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7 Scopus citations

Abstract

Hydrothermal reactions were used in the preparation of a series of bimetallic organic-inorganic hybrid materials of the M(II)/V_xO _y/organonitrogen ligand class. Compound 1, [{Cu₂(bpa) ₂(C₂O₄)}₂V₄O ₁₂]·H₂O, is molecular, while [{Cu(terpy)} ₂V₆O₁₇] (2), [Cu₂(bpyrm)V ₄O₁₂] (4) and [{Cu(phen)(H₂O) ₂}VOF₄(H₂O)]·2H₂O (5) are two-dimensional, three-dimensional and one-dimensional, respectively (bpa = 2,2′-bipyridylamine; terpy = 2,2′:6,2″-terpyridine; bpyrm = 2,2′-bipyrimidine; phen = 1,10-phenanthroline). In contrast to the 2-D structure of 2, the Ni(II) analogue [{Ni(terpy)}₂V₄O ₁₂]·2H₂O (3) is one-dimensional. The {V ₄O₁₂}^4- cluster is a building block of structures 1, 3, and 4 while 2 is constructed from {V₆O ₁₇}^4- rings.

Original language	English (US)
Pages (from-to)	2912-2919
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	363
Issue number	12
DOIs	https://doi.org/10.1016/j.ica.2010.03.036
State	Published - Oct 15 2010

Keywords

Copper-vanadates
Hydrothermal synthesis
Organic-inorganic hybrid materials
Organonitrogen ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2010.03.036

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title = "Organic-inorganic hybrid materials: Ligand influences on the structural chemistry of copper-vanadates",

abstract = "Hydrothermal reactions were used in the preparation of a series of bimetallic organic-inorganic hybrid materials of the M(II)/VxO y/organonitrogen ligand class. Compound 1, [{Cu2(bpa) 2(C2O4)}2V4O 12]·H2O, is molecular, while [{Cu(terpy)} 2V6O17] (2), [Cu2(bpyrm)V 4O12] (4) and [{Cu(phen)(H2O) 2}VOF4(H2O)]·2H2O (5) are two-dimensional, three-dimensional and one-dimensional, respectively (bpa = 2,2′-bipyridylamine; terpy = 2,2′:6,2″-terpyridine; bpyrm = 2,2′-bipyrimidine; phen = 1,10-phenanthroline). In contrast to the 2-D structure of 2, the Ni(II) analogue [{Ni(terpy)}2V4O 12]·2H2O (3) is one-dimensional. The {V 4O12}4- cluster is a building block of structures 1, 3, and 4 while 2 is constructed from {V6O 17}4- rings.",

keywords = "Copper-vanadates, Hydrothermal synthesis, Organic-inorganic hybrid materials, Organonitrogen ligands",

author = "Paul Deburgomaster and Jon Zubieta",

note = "Funding Information: This work was supported by a Grant from the National Science Foundation ( CHE-0907787 ). ",

year = "2010",

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doi = "10.1016/j.ica.2010.03.036",

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T1 - Organic-inorganic hybrid materials

T2 - Ligand influences on the structural chemistry of copper-vanadates

AU - Deburgomaster, Paul

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a Grant from the National Science Foundation ( CHE-0907787 ).

PY - 2010/10/15

Y1 - 2010/10/15

N2 - Hydrothermal reactions were used in the preparation of a series of bimetallic organic-inorganic hybrid materials of the M(II)/VxO y/organonitrogen ligand class. Compound 1, [{Cu2(bpa) 2(C2O4)}2V4O 12]·H2O, is molecular, while [{Cu(terpy)} 2V6O17] (2), [Cu2(bpyrm)V 4O12] (4) and [{Cu(phen)(H2O) 2}VOF4(H2O)]·2H2O (5) are two-dimensional, three-dimensional and one-dimensional, respectively (bpa = 2,2′-bipyridylamine; terpy = 2,2′:6,2″-terpyridine; bpyrm = 2,2′-bipyrimidine; phen = 1,10-phenanthroline). In contrast to the 2-D structure of 2, the Ni(II) analogue [{Ni(terpy)}2V4O 12]·2H2O (3) is one-dimensional. The {V 4O12}4- cluster is a building block of structures 1, 3, and 4 while 2 is constructed from {V6O 17}4- rings.

AB - Hydrothermal reactions were used in the preparation of a series of bimetallic organic-inorganic hybrid materials of the M(II)/VxO y/organonitrogen ligand class. Compound 1, [{Cu2(bpa) 2(C2O4)}2V4O 12]·H2O, is molecular, while [{Cu(terpy)} 2V6O17] (2), [Cu2(bpyrm)V 4O12] (4) and [{Cu(phen)(H2O) 2}VOF4(H2O)]·2H2O (5) are two-dimensional, three-dimensional and one-dimensional, respectively (bpa = 2,2′-bipyridylamine; terpy = 2,2′:6,2″-terpyridine; bpyrm = 2,2′-bipyrimidine; phen = 1,10-phenanthroline). In contrast to the 2-D structure of 2, the Ni(II) analogue [{Ni(terpy)}2V4O 12]·2H2O (3) is one-dimensional. The {V 4O12}4- cluster is a building block of structures 1, 3, and 4 while 2 is constructed from {V6O 17}4- rings.

KW - Copper-vanadates

KW - Hydrothermal synthesis

KW - Organic-inorganic hybrid materials

KW - Organonitrogen ligands

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Organic-inorganic hybrid materials: Ligand influences on the structural chemistry of copper-vanadates

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