Abstract
Hydrothermal reactions were used in the preparation of a series of bimetallic organic-inorganic hybrid materials of the M(II)/VxO y/organonitrogen ligand class. Compound 1, [{Cu2(bpa) 2(C2O4)}2V4O 12]·H2O, is molecular, while [{Cu(terpy)} 2V6O17] (2), [Cu2(bpyrm)V 4O12] (4) and [{Cu(phen)(H2O) 2}VOF4(H2O)]·2H2O (5) are two-dimensional, three-dimensional and one-dimensional, respectively (bpa = 2,2′-bipyridylamine; terpy = 2,2′:6,2″-terpyridine; bpyrm = 2,2′-bipyrimidine; phen = 1,10-phenanthroline). In contrast to the 2-D structure of 2, the Ni(II) analogue [{Ni(terpy)}2V4O 12]·2H2O (3) is one-dimensional. The {V 4O12}4- cluster is a building block of structures 1, 3, and 4 while 2 is constructed from {V6O 17}4- rings.
Original language | English (US) |
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Pages (from-to) | 2912-2919 |
Number of pages | 8 |
Journal | Inorganica Chimica Acta |
Volume | 363 |
Issue number | 12 |
DOIs | |
State | Published - Oct 15 2010 |
Keywords
- Copper-vanadates
- Hydrothermal synthesis
- Organic-inorganic hybrid materials
- Organonitrogen ligands
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry