Organic-inorganic composite oxide phases: One-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu2(triazolate)2(H2O)2}Mo 4O13]

Douglas Hagrman; Jon Zubieta

doi:10.1039/a804689a

Organic-inorganic composite oxide phases: One-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu₂(triazolate)₂(H₂O)₂}Mo ₄O₁₃]

Douglas Hagrman, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

The hydrothermal reaction of MoO₃, CuSO₄·5H₂O, 1,2,4-triazole and H₂O produces a 50% yield of [{Cu₂-(triazolate)₂(H₂O)₂}Mo ₄O₁₃], a material constructed from {Mo₄O₁₃}_n^2n- chains entrained within the three dimensional framework provided by the {Cu₂(triazolate)₂(H₂O)₂} _n²ⁿ⁺ polymeric complex.

Original language	English (US)
Pages (from-to)	2005-2006
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a804689a
State	Published - Sep 21 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/a804689a

Cite this

@article{473fc54bfbb742f8b42b6e0ffddcf895,

title = "Organic-inorganic composite oxide phases: One-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu2(triazolate)2(H2O)2}Mo 4O13]",

abstract = "The hydrothermal reaction of MoO3, CuSO4·5H2O, 1,2,4-triazole and H2O produces a 50% yield of [{Cu2-(triazolate)2(H2O)2}Mo 4O13], a material constructed from {Mo4O13}n2n- chains entrained within the three dimensional framework provided by the {Cu2(triazolate)2(H2O)2} n2n+ polymeric complex.",

author = "Douglas Hagrman and Jon Zubieta",

year = "1998",

month = sep,

day = "21",

doi = "10.1039/a804689a",

language = "English (US)",

pages = "2005--2006",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - Organic-inorganic composite oxide phases

T2 - One-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu2(triazolate)2(H2O)2}Mo 4O13]

AU - Hagrman, Douglas

AU - Zubieta, Jon

PY - 1998/9/21

Y1 - 1998/9/21

N2 - The hydrothermal reaction of MoO3, CuSO4·5H2O, 1,2,4-triazole and H2O produces a 50% yield of [{Cu2-(triazolate)2(H2O)2}Mo 4O13], a material constructed from {Mo4O13}n2n- chains entrained within the three dimensional framework provided by the {Cu2(triazolate)2(H2O)2} n2n+ polymeric complex.

AB - The hydrothermal reaction of MoO3, CuSO4·5H2O, 1,2,4-triazole and H2O produces a 50% yield of [{Cu2-(triazolate)2(H2O)2}Mo 4O13], a material constructed from {Mo4O13}n2n- chains entrained within the three dimensional framework provided by the {Cu2(triazolate)2(H2O)2} n2n+ polymeric complex.

UR - http://www.scopus.com/inward/record.url?scp=21844466712&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=21844466712&partnerID=8YFLogxK

U2 - 10.1039/a804689a

DO - 10.1039/a804689a

M3 - Article

AN - SCOPUS:21844466712

SN - 1359-7345

SP - 2005

EP - 2006

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Organic-inorganic composite oxide phases: One-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu₂(triazolate)₂(H₂O)₂}Mo ₄O₁₃]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this