Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties

Burak Ay; Emel Yildiz; Jon A Zubieta

doi:10.1109/NAP.2017.8190251

Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties

Burak Ay, Emel Yildiz, Jon A Zubieta

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

In this study, three mesoporous nanopolymers, namely, [Ln(2,5-pydc)(2-pydc)]n (Ln = Sm (1), Nd (2) and Eu (3), 2,5-pydc = 2,5-pyridinedicarboxylic acid) have been synthesized under hydrothermal conditions. The synthesized coordination polymers were characterized by the elemental analysis, inductively coupled plasma (ICP), fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), single crystal X-ray diffraction and powder X-ray diffraction (PXRD) analysis. For morphological analysis, field emission scanning electron microscopy (FESEM) and brunauer, emmett and teller (BET) were used. The compounds are isostructural and lanthanide complexes contain three-dimensional infinite Ln-O-Ln chains. Photoluminescence properties and thermal stabilities of the compounds have been investigated. All the polymers showed high thermal stability. The polymers 1-3 exhibit luminescent emission bands at 624, 579 and 606 nm at room temperature when excited at 320 nm, respectively.

Original language	English (US)
Title of host publication	Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials
Subtitle of host publication	Applications and Properties, NAP 2017
Publisher	Institute of Electrical and Electronics Engineers Inc.
Volume	2017-January
ISBN (Electronic)	9781538628102
DOIs	https://doi.org/10.1109/NAP.2017.8190251
State	Published - Dec 12 2017
Event	7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017 - Zatoka, Ukraine Duration: Sep 10 2017 → Sep 15 2017

Other

Other	7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017
Country	Ukraine
City	Zatoka
Period	9/10/17 → 9/15/17

Keywords

Hydrothermal synthesis
Lanthanides
Luminescence
Mesoporous nanopolymers

ASJC Scopus subject areas

Materials Science (miscellaneous)
Mechanics of Materials

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Ay, B., Yildiz, E., & Zubieta, J. A. (2017). Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties. In Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017 (Vol. 2017-January). [8190251] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/NAP.2017.8190251

Ordered nanopolymer structures including lanthanide-organic frameworks : Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties. / Ay, Burak; Yildiz, Emel; Zubieta, Jon A.

Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Vol. 2017-January Institute of Electrical and Electronics Engineers Inc., 2017. 8190251.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Ay, B, Yildiz, E & Zubieta, JA 2017, Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties. in Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. vol. 2017-January, 8190251, Institute of Electrical and Electronics Engineers Inc., 7th IEEE International Conference on Nanomaterials: Applications and Properties, NAP 2017, Zatoka, Ukraine, 9/10/17. https://doi.org/10.1109/NAP.2017.8190251

Ay B, Yildiz E, Zubieta JA. Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties. In Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Vol. 2017-January. Institute of Electrical and Electronics Engineers Inc. 2017. 8190251 https://doi.org/10.1109/NAP.2017.8190251

Ay, Burak ; Yildiz, Emel ; Zubieta, Jon A. / Ordered nanopolymer structures including lanthanide-organic frameworks : Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties. Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017. Vol. 2017-January Institute of Electrical and Electronics Engineers Inc., 2017.

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AB - In this study, three mesoporous nanopolymers, namely, [Ln(2,5-pydc)(2-pydc)]n (Ln = Sm (1), Nd (2) and Eu (3), 2,5-pydc = 2,5-pyridinedicarboxylic acid) have been synthesized under hydrothermal conditions. The synthesized coordination polymers were characterized by the elemental analysis, inductively coupled plasma (ICP), fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), single crystal X-ray diffraction and powder X-ray diffraction (PXRD) analysis. For morphological analysis, field emission scanning electron microscopy (FESEM) and brunauer, emmett and teller (BET) were used. The compounds are isostructural and lanthanide complexes contain three-dimensional infinite Ln-O-Ln chains. Photoluminescence properties and thermal stabilities of the compounds have been investigated. All the polymers showed high thermal stability. The polymers 1-3 exhibit luminescent emission bands at 624, 579 and 606 nm at room temperature when excited at 320 nm, respectively.

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