Optical Resolution of "Weakly Chiral" P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me)

H. P. Abicht; J. T. Spencer; J. G. Verkade

doi:10.1021/ic00208a006

Optical Resolution of "Weakly Chiral" P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me)

H. P. Abicht, J. T. Spencer, J. G. Verkade

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The first resolution of an enantiomeric phosphorus triester, namely P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me) (1), is reported. Compound 1 is remarkably stable to substituent exchange when pure. The unusually distant seat of chirality from the phosphorus appears to have interesting consequences on some chirality-dependent phenomena at this atom.

Original language	English (US)
Pages (from-to)	2132-2134
Number of pages	3
Journal	Inorganic Chemistry
Volume	24
Issue number	14
DOIs	https://doi.org/10.1021/ic00208a006
State	Published - Jul 1 1985
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00208a006

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abstract = "The first resolution of an enantiomeric phosphorus triester, namely P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me) (1), is reported. Compound 1 is remarkably stable to substituent exchange when pure. The unusually distant seat of chirality from the phosphorus appears to have interesting consequences on some chirality-dependent phenomena at this atom.",

author = "Abicht, {H. P.} and Spencer, {J. T.} and Verkade, {J. G.}",

year = "1985",

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AU - Abicht, H. P.

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AU - Verkade, J. G.

PY - 1985/7/1

Y1 - 1985/7/1

N2 - The first resolution of an enantiomeric phosphorus triester, namely P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me) (1), is reported. Compound 1 is remarkably stable to substituent exchange when pure. The unusually distant seat of chirality from the phosphorus appears to have interesting consequences on some chirality-dependent phenomena at this atom.

AB - The first resolution of an enantiomeric phosphorus triester, namely P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me) (1), is reported. Compound 1 is remarkably stable to substituent exchange when pure. The unusually distant seat of chirality from the phosphorus appears to have interesting consequences on some chirality-dependent phenomena at this atom.

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JF - Inorganic Chemistry

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Optical Resolution of "Weakly Chiral" P(OPh)(OC6H4-p-Cl)(OC6H4-p-Me)

Abstract

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