One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)

Pamela J. Zapf; Christopher J. Warren; Robert C. Haushalter; Jon Zubieta

doi:10.1039/a702765f

One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}²⁺ fragments (M = Co, Ni, Cu)

Pamela J. Zapf, Christopher J. Warren, Robert C. Haushalter, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

199 Scopus citations

Abstract

Hydrothermal reactions of Na₂MoO₄·2H₂O and MoO₃ with MCl₂·xH₂O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}²⁺ groups and represented by the formulae [M(bpy)_x-(H₂O)_yMo_nO_3n+1] (n = 2, M = Cu, x = 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).

Original language	English (US)
Pages (from-to)	1543-1544
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/a702765f
State	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/a702765f

Cite this

One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}²⁺ fragments (M = Co, Ni, Cu). / Zapf, Pamela J.; Warren, Christopher J.; Haushalter, Robert C. et al.
In: Chemical Communications, No. 16, 1997, p. 1543-1544.

Research output: Contribution to journal › Article › peer-review

@article{04edbe7c408342ffadf59a7a609e8b12,

title = "One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)",

abstract = "Hydrothermal reactions of Na2MoO4·2H2O and MoO3 with MCl2·xH2O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}2+ groups and represented by the formulae [M(bpy)x-(H2O)yMonO3n+1] (n = 2, M = Cu, x = 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).",

author = "Zapf, {Pamela J.} and Warren, {Christopher J.} and Haushalter, {Robert C.} and Jon Zubieta",

year = "1997",

doi = "10.1039/a702765f",

language = "English (US)",

pages = "1543--1544",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)

AU - Zapf, Pamela J.

AU - Warren, Christopher J.

AU - Haushalter, Robert C.

AU - Zubieta, Jon

PY - 1997

Y1 - 1997

N2 - Hydrothermal reactions of Na2MoO4·2H2O and MoO3 with MCl2·xH2O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}2+ groups and represented by the formulae [M(bpy)x-(H2O)yMonO3n+1] (n = 2, M = Cu, x = 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).

AB - Hydrothermal reactions of Na2MoO4·2H2O and MoO3 with MCl2·xH2O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}2+ groups and represented by the formulae [M(bpy)x-(H2O)yMonO3n+1] (n = 2, M = Cu, x = 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).

UR - http://www.scopus.com/inward/record.url?scp=0002831940&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002831940&partnerID=8YFLogxK

U2 - 10.1039/a702765f

DO - 10.1039/a702765f

M3 - Article

AN - SCOPUS:0002831940

SN - 1359-7345

SP - 1543

EP - 1544

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}²⁺ fragments (M = Co, Ni, Cu)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this