One- and two-dimensional organic-inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)

Pamela J. Zapf, Christopher J. Warren, Robert C. Haushalter, Jon Zubieta

Research output: Contribution to journalArticle

192 Scopus citations

Abstract

Hydrothermal reactions of Na2MoO4·2H2O and MoO3 with MCl2·xH2O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}2+ groups and represented by the formulae [M(bpy)x-(H2O)yMonO3n+1] (n = 2, M = Cu, x = 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).

Original languageEnglish (US)
Pages (from-to)1543-1544
Number of pages2
JournalChemical Communications
Issue number16
DOIs
StatePublished - Jan 1 1997

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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