TY - JOUR
T1 - Octamolybdate subunits as building blocks in the hydrothermal synthesis of organically templated mixed metal oxides (see abstract)
AU - Rarig, Randy S.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by grant CHE 9987471 from the National Science Foundation.
Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2003/1/1
Y1 - 2003/1/1
N2 - The hydrothermal reactions of MoO3, an appropriate Cu(II) source, and a dipodal nitrogen donor ligand yielded a series of bimetallic oxides [Cu2Mo4O13(3,3′-bipy)2] ·H2O(1·H2O), [CuMo4O13(Hdipyreth)] (2), and [Cu(dpp)]2[Cu2(α-Mo8O26) (dpp)2]·2H2O (3·2H2O). (3,3′-bipy = 3,3′-bipyridine; dipyreth = 1,2-bis(2-pyridyl)ethylene; dpp = 4,4′-trimethylenedipyridine). The materials 1· H2O and 2 are constructed from octamolybdate clusters linked through copper-ligand subunits, while 3·2H2O exhibits fused octamolybdate building blocks in a two-dimensional molybdate chain.
AB - The hydrothermal reactions of MoO3, an appropriate Cu(II) source, and a dipodal nitrogen donor ligand yielded a series of bimetallic oxides [Cu2Mo4O13(3,3′-bipy)2] ·H2O(1·H2O), [CuMo4O13(Hdipyreth)] (2), and [Cu(dpp)]2[Cu2(α-Mo8O26) (dpp)2]·2H2O (3·2H2O). (3,3′-bipy = 3,3′-bipyridine; dipyreth = 1,2-bis(2-pyridyl)ethylene; dpp = 4,4′-trimethylenedipyridine). The materials 1· H2O and 2 are constructed from octamolybdate clusters linked through copper-ligand subunits, while 3·2H2O exhibits fused octamolybdate building blocks in a two-dimensional molybdate chain.
KW - Hydrothermal reactions
KW - Hydrothermal synthesis
KW - Mixed metal oxides
KW - Octamolybdate subunits
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U2 - 10.1016/S0277-5387(02)01268-8
DO - 10.1016/S0277-5387(02)01268-8
M3 - Article
AN - SCOPUS:0037966073
VL - 22
SP - 177
EP - 188
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 1
ER -