Abstract
The hydrothermal reactions of MoO3, an appropriate Cu(II) source, and a dipodal nitrogen donor ligand yielded a series of bimetallic oxides [Cu2Mo4O13(3,3′-bipy)2] ·H2O(1·H2O), [CuMo4O13(Hdipyreth)] (2), and [Cu(dpp)]2[Cu2(α-Mo8O26) (dpp)2]·2H2O (3·2H2O). (3,3′-bipy = 3,3′-bipyridine; dipyreth = 1,2-bis(2-pyridyl)ethylene; dpp = 4,4′-trimethylenedipyridine). The materials 1· H2O and 2 are constructed from octamolybdate clusters linked through copper-ligand subunits, while 3·2H2O exhibits fused octamolybdate building blocks in a two-dimensional molybdate chain.
Original language | English (US) |
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Pages (from-to) | 177-188 |
Number of pages | 12 |
Journal | Polyhedron |
Volume | 22 |
Issue number | 1 |
DOIs | |
State | Published - Jan 1 2003 |
Keywords
- Hydrothermal reactions
- Hydrothermal synthesis
- Mixed metal oxides
- Octamolybdate subunits
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry