Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[VIII2(PO4)(HPO4)2(H2O)2] and of the Mixed-Valence Species K[(VIVO)VIII(HPO4)3(H2O)2]

Robert C. Haushalter; Zhanwen Wang; Mark E. Thompson; Jon Zubieta

doi:10.1021/ic00069a026

Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[V^III₂(PO₄)(HPO₄)₂(H₂O)₂] and of the Mixed-Valence Species K[(V^IVO)V^III(HPO₄)₃(H₂O)₂]

Robert C. Haushalter, Zhanwen Wang, Mark E. Thompson, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The cesium vanadium phosphate Cs[V^III₂(PO₄) (HPO₄)₂(H₂O)₂] (1) and the potassium vanadium phosphate K[(V^IVO)-V^III(HPO₄)₃(H₂O)₂] (2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray methods. Green phosphate 1 is monoclinic, space group P2₁/a, with a = 10.004(1) Å, b = 17.812(3) Å, c = 6.370(2) Å, β = 97.02(2)°, and Z = 4, while green phosphate 2 is monoclinic, space group P2₁/n, with a = 6.399(3) Å, b = 10.275(2) Å, c = 17.810(2) Å, β = 96.12(2),° and Z = 4. These new reduced vanadium phosphates, built up from corner-sharing VO₆ octahedra and PO₄ tetrahedra, have anionic, three-dimensional framework structures that contain Cs⁺- and K⁺-filled voids.

Original language	English (US)
Pages (from-to)	3700-3704
Number of pages	5
Journal	Inorganic Chemistry
Volume	32
Issue number	17
DOIs	https://doi.org/10.1021/ic00069a026
State	Published - 1993

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Physical and Theoretical Chemistry
Inorganic Chemistry

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Haushalter, R. C., Wang, Z., Thompson, M. E., & Zubieta, J. (1993). Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[V^III₂(PO₄)(HPO₄)₂(H₂O)₂] and of the Mixed-Valence Species K[(V^IVO)V^III(HPO₄)₃(H₂O)₂]. Inorganic Chemistry, 32(17), 3700-3704. https://doi.org/10.1021/ic00069a026

Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[V^III₂(PO₄)(HPO₄)₂(H₂O)₂] and of the Mixed-Valence Species K[(V^IVO)V^III(HPO₄)₃(H₂O)₂]. / Haushalter, Robert C.; Wang, Zhanwen; Thompson, Mark E. et al.
In: Inorganic Chemistry, Vol. 32, No. 17, 1993, p. 3700-3704.

Research output: Contribution to journal › Article › peer-review

Haushalter, RC, Wang, Z, Thompson, ME & Zubieta, J 1993, 'Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[V^III₂(PO₄)(HPO₄)₂(H₂O)₂] and of the Mixed-Valence Species K[(V^IVO)V^III(HPO₄)₃(H₂O)₂]', Inorganic Chemistry, vol. 32, no. 17, pp. 3700-3704. https://doi.org/10.1021/ic00069a026

Haushalter, Robert C. ; Wang, Zhanwen ; Thompson, Mark E. et al. / Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[V^III₂(PO₄)(HPO₄)₂(H₂O)₂] and of the Mixed-Valence Species K[(V^IVO)V^III(HPO₄)₃(H₂O)₂]. In: Inorganic Chemistry. 1993 ; Vol. 32, No. 17. pp. 3700-3704.

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title = "Octahedral-Tetrahedral Framework Solids of the Vanadium Phosphate System. Hydrothermal Syntheses and Crystal Structures of the Vanadium(III) Phosphate Cs[VIII2(PO4)(HPO4)2(H2O)2] and of the Mixed-Valence Species K[(VIVO)VIII(HPO4)3(H2O)2]",

abstract = "The cesium vanadium phosphate Cs[VIII2(PO4) (HPO4)2(H2O)2] (1) and the potassium vanadium phosphate K[(VIVO)-VIII(HPO4)3(H2O)2] (2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray methods. Green phosphate 1 is monoclinic, space group P21/a, with a = 10.004(1) {\AA}, b = 17.812(3) {\AA}, c = 6.370(2) {\AA}, β = 97.02(2)°, and Z = 4, while green phosphate 2 is monoclinic, space group P21/n, with a = 6.399(3) {\AA}, b = 10.275(2) {\AA}, c = 17.810(2) {\AA}, β = 96.12(2),° and Z = 4. These new reduced vanadium phosphates, built up from corner-sharing VO6 octahedra and PO4 tetrahedra, have anionic, three-dimensional framework structures that contain Cs+- and K+-filled voids.",

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N2 - The cesium vanadium phosphate Cs[VIII2(PO4) (HPO4)2(H2O)2] (1) and the potassium vanadium phosphate K[(VIVO)-VIII(HPO4)3(H2O)2] (2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray methods. Green phosphate 1 is monoclinic, space group P21/a, with a = 10.004(1) Å, b = 17.812(3) Å, c = 6.370(2) Å, β = 97.02(2)°, and Z = 4, while green phosphate 2 is monoclinic, space group P21/n, with a = 6.399(3) Å, b = 10.275(2) Å, c = 17.810(2) Å, β = 96.12(2),° and Z = 4. These new reduced vanadium phosphates, built up from corner-sharing VO6 octahedra and PO4 tetrahedra, have anionic, three-dimensional framework structures that contain Cs+- and K+-filled voids.

AB - The cesium vanadium phosphate Cs[VIII2(PO4) (HPO4)2(H2O)2] (1) and the potassium vanadium phosphate K[(VIVO)-VIII(HPO4)3(H2O)2] (2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray methods. Green phosphate 1 is monoclinic, space group P21/a, with a = 10.004(1) Å, b = 17.812(3) Å, c = 6.370(2) Å, β = 97.02(2)°, and Z = 4, while green phosphate 2 is monoclinic, space group P21/n, with a = 6.399(3) Å, b = 10.275(2) Å, c = 17.810(2) Å, β = 96.12(2),° and Z = 4. These new reduced vanadium phosphates, built up from corner-sharing VO6 octahedra and PO4 tetrahedra, have anionic, three-dimensional framework structures that contain Cs+- and K+-filled voids.

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