TY - JOUR
T1 - Observation and assignment of D7,°7, and S7 Rydberg series of molybdenum atoms by multiphoton dissociation and ionization spectroscopy of organometallic molecules
AU - Samoriski, Brian
AU - Chaiken, J.
N1 - Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 1988
Y1 - 1988
N2 - The multiphoton ionization spectra of several arene molybdenum tricarbonyls have been measured in the region 350420 nm. These spectra exhibit allowed, two-photon resonant ns 7S3 and nd 7DJ Rydberg series of neutral bare molybdenum atoms. Furthermore, the electric field inherent to the multiphoton ionization experiment also permits observation of the nominally forbidden np 7P°J Rydberg series. A nonlinear least-squares regression of the Rydberg equation was used to obtain an improved ionization potential of molybdenum and the quantum defects of the three series.
AB - The multiphoton ionization spectra of several arene molybdenum tricarbonyls have been measured in the region 350420 nm. These spectra exhibit allowed, two-photon resonant ns 7S3 and nd 7DJ Rydberg series of neutral bare molybdenum atoms. Furthermore, the electric field inherent to the multiphoton ionization experiment also permits observation of the nominally forbidden np 7P°J Rydberg series. A nonlinear least-squares regression of the Rydberg equation was used to obtain an improved ionization potential of molybdenum and the quantum defects of the three series.
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U2 - 10.1103/PhysRevA.38.3498
DO - 10.1103/PhysRevA.38.3498
M3 - Article
AN - SCOPUS:17044435354
SN - 1050-2947
VL - 38
SP - 3498
EP - 3503
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
IS - 7
ER -