Abstract
The synthesis and characterization of a family of novel alkaline earth metal stannides, in addition to tri- and pentastannanes are described. [Ba(18-crown-6)(HMPA)2][SnPh3]2 (4), [Ca(18-crown-6)(HMPA)2][Sn(SnPh3)3]2 (5), and [Sr(18-crown-6)(HMPA)2][Sn(SnPh3)3]2 (6) were synthesized by insertion of the corresponding alkaline earth metals into the tin-tin bond of hexaphenyldistannane. Ph3SnSnPh2SnPh3 (7), and Sn(SnPh3)4 (8) became available by treating 4 with diphenyldichlorostannane. All compounds were studied by NMR spectroscopy, and X-ray crystallography. The stannanes 7 and 8 were also characterized by elemental analysis.
Original language | English (US) |
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Pages (from-to) | 139-147 |
Number of pages | 9 |
Journal | Journal of Organometallic Chemistry |
Volume | 613 |
Issue number | 2 |
DOIs | |
State | Published - Nov 3 2000 |
Keywords
- Alkaline earth metal stannides
- Sn-NMR spectroscopy
- Stannanes
- Structure elucidation
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry