Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2] 2[Sb4Cl12O]}2·2C 6H6

Arnold L. Rheingold; Albert G. Landers; Philip Dahlstrom; Jon Zubieta

doi:10.1039/C39790000143

Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C₅H₅)₂] ₂[Sb₄Cl₁₂O]}₂·2C ₆H₆

Arnold L. Rheingold, Albert G. Landers, Philip Dahlstrom, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The product of the reaction between SbCl₃ and Fe(η-C ₅H₅)₂ in benzene is shown by X-ray crystallography to possess an octameric unit [Sb₄Cl ₁₂O]₂^4-, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.

Original language	English (US)
Pages (from-to)	143-144
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39790000143
State	Published - 1979
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2] 2[Sb4Cl12O]}2·2C 6H6",

abstract = "The product of the reaction between SbCl3 and Fe(η-C 5H5)2 in benzene is shown by X-ray crystallography to possess an octameric unit [Sb4Cl 12O]24-, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.",

author = "Rheingold, {Arnold L.} and Landers, {Albert G.} and Philip Dahlstrom and Jon Zubieta",

year = "1979",

doi = "10.1039/C39790000143",

language = "English (US)",

pages = "143--144",

journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "3",

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T1 - Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2] 2[Sb4Cl12O]}2·2C 6H6

AU - Rheingold, Arnold L.

AU - Landers, Albert G.

AU - Dahlstrom, Philip

AU - Zubieta, Jon

PY - 1979

Y1 - 1979

N2 - The product of the reaction between SbCl3 and Fe(η-C 5H5)2 in benzene is shown by X-ray crystallography to possess an octameric unit [Sb4Cl 12O]24-, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.

AB - The product of the reaction between SbCl3 and Fe(η-C 5H5)2 in benzene is shown by X-ray crystallography to possess an octameric unit [Sb4Cl 12O]24-, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.

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DO - 10.1039/C39790000143

M3 - Article

AN - SCOPUS:37049102336

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Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C₅H₅)₂] ₂[Sb₄Cl₁₂O]}₂·2C ₆H₆

Abstract

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