Novel antimony cluster displaying a quadruply bridging chloride. X-Ray crystal structure of {[Fe(η-C5H5)2] 2[Sb4Cl12O]}2·2C 6H6

Arnold L. Rheingold, Albert G. Landers, Philip Dahlstrom, Jon Zubieta

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

The product of the reaction between SbCl3 and Fe(η-C 5H5)2 in benzene is shown by X-ray crystallography to possess an octameric unit [Sb4Cl 12O]24-, with terminal and bridging chloride groups and bridging oxo-groups; the ferricenium cations are shown to adopt the eclipsed configurations.

Original languageEnglish (US)
Pages (from-to)143-144
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number3
DOIs
StatePublished - Dec 1 1979
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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