New solids from old clusters: Syntheses and structures of [Cu(en)2]2[Mo8O26], [Cu(enMe)2]3[V15O36Cl] · 2.5H2O and Cs0.5[Ni(en)2]3[V18O42Cl] · 2en · 6H2O

Jeffrey R.D. DeBord, Robert C. Haushalter, Linda M. Meyer, David J. Rose, Pamela J. Zapf, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

179 Scopus citations


One-dimensional and two-dimensional solids consisting of polyoxoanions bridged by {M(LL)2}2+ groups have been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography.

Original languageEnglish (US)
Pages (from-to)165-168
Number of pages4
JournalInorganica Chimica Acta
Issue number2
StatePublished - Mar 31 1997


  • Copper complexes
  • Crystal structures
  • One-dimensional complexes
  • Polyoxoanion complexes
  • Two-dimensional complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


Dive into the research topics of 'New solids from old clusters: Syntheses and structures of [Cu(en)<sub>2</sub>]<sub>2</sub>[Mo<sub>8</sub>O<sub>26</sub>], [Cu(enMe)<sub>2</sub>]<sub>3</sub>[V<sub>15</sub>O<sub>36</sub>Cl] · 2.5H<sub>2</sub>O and Cs<sub>0.5</sub>[Ni(en)<sub>2</sub>]<sub>3</sub>[V<sub>18</sub>O<sub>42</sub>Cl] · 2en · 6H<sub>2</sub>O'. Together they form a unique fingerprint.

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