New solids from old clusters: Syntheses and structures of [Cu(en)2]2[Mo8O26], [Cu(enMe)2]3[V15O36Cl] · 2.5H2O and Cs0.5[Ni(en)2]3[V18O42Cl] · 2en · 6H2O

Jeffrey R.D. DeBord; Robert C. Haushalter; Linda M. Meyer; David J. Rose; Pamela J. Zapf; Jon Zubieta

doi:10.1016/S0020-1693(97)05472-8

New solids from old clusters: Syntheses and structures of [Cu(en)₂]₂[Mo₈O₂₆], [Cu(enMe)₂]₃[V₁₅O₃₆Cl] · 2.5H₂O and Cs_0.5[Ni(en)₂]₃[V₁₈O₄₂Cl] · 2en · 6H₂O

Jeffrey R.D. DeBord, Robert C. Haushalter, Linda M. Meyer, David J. Rose, Pamela J. Zapf, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

180 Scopus citations

Abstract

One-dimensional and two-dimensional solids consisting of polyoxoanions bridged by {M(LL)₂}²⁺ groups have been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography.

Original language	English (US)
Pages (from-to)	165-168
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	256
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(97)05472-8
State	Published - Mar 31 1997

Keywords

Copper complexes
Crystal structures
One-dimensional complexes
Polyoxoanion complexes
Two-dimensional complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(97)05472-8

Cite this

@article{79bbb4d2fb264c3db0b48ca5324654c5,

title = "New solids from old clusters: Syntheses and structures of [Cu(en)2]2[Mo8O26], [Cu(enMe)2]3[V15O36Cl] · 2.5H2O and Cs0.5[Ni(en)2]3[V18O42Cl] · 2en · 6H2O",

abstract = "One-dimensional and two-dimensional solids consisting of polyoxoanions bridged by {M(LL)2}2+ groups have been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography.",

keywords = "Copper complexes, Crystal structures, One-dimensional complexes, Polyoxoanion complexes, Two-dimensional complexes",

author = "DeBord, {Jeffrey R.D.} and Haushalter, {Robert C.} and Meyer, {Linda M.} and Rose, {David J.} and Zapf, {Pamela J.} and Jon Zubieta",

note = "Funding Information: The work at Syracuse University was supported by NSF Grant CHE 9 617 232.",

year = "1997",

month = mar,

day = "31",

doi = "10.1016/S0020-1693(97)05472-8",

language = "English (US)",

volume = "256",

pages = "165--168",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - New solids from old clusters

T2 - Syntheses and structures of [Cu(en)2]2[Mo8O26], [Cu(enMe)2]3[V15O36Cl] · 2.5H2O and Cs0.5[Ni(en)2]3[V18O42Cl] · 2en · 6H2O

AU - DeBord, Jeffrey R.D.

AU - Haushalter, Robert C.

AU - Meyer, Linda M.

AU - Rose, David J.

AU - Zapf, Pamela J.

AU - Zubieta, Jon

N1 - Funding Information: The work at Syracuse University was supported by NSF Grant CHE 9 617 232.

PY - 1997/3/31

Y1 - 1997/3/31

N2 - One-dimensional and two-dimensional solids consisting of polyoxoanions bridged by {M(LL)2}2+ groups have been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography.

AB - One-dimensional and two-dimensional solids consisting of polyoxoanions bridged by {M(LL)2}2+ groups have been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography.

KW - Copper complexes

KW - Crystal structures

KW - One-dimensional complexes

KW - Polyoxoanion complexes

KW - Two-dimensional complexes

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U2 - 10.1016/S0020-1693(97)05472-8

DO - 10.1016/S0020-1693(97)05472-8

M3 - Article

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SN - 0020-1693

VL - 256

SP - 165

EP - 168

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -