Nacre-inspired design of graphene oxide–polydopamine nanocomposites for enhanced mechanical properties and multi-functionalities

Chun Teh Chen, Francisco J. Martin-Martinez, Shengjie Ling, Zhao Qin, Markus J. Buehler

Research output: Contribution to journalLetter

21 Scopus citations

Abstract

Inspired by the hierarchical structure of nacre and the robust adhesive ability of mussel threads, graphene oxide–polydopamine (GO–PDA) nanocomposites are designed and synthesized to achieve enhanced mechanical properties and to provide additional functionalities. Here we report a joint experimental/computational investigation of GO–PDA nanocomposites, proposing a probable chemical reduction mechanism of PDA to convert GO to reduced GO (rGO), which helps increase the electrical conductivity. The most stable chemical connection between PDA and GO is also proposed. Our artificial nacre-like GO–PDA nanocomposites are shown to have higher tensile strength and toughness compared to natural nacre. The pulling tests conducted by molecular dynamics simulations, which are supported by our experiments, reveal that the enhanced mechanical strength of GO–PDA nanocomposites mainly originates from the additional non-covalent interactions provided by PDA. The humidity-driven shrinking mechanism of GO–PDA nanocomposites due to non-uniform stresses on the GO–PDA sheets is also discovered in our simulations and supported by our experiments. The findings in this work can help improve and tune the properties of GO–PDA nanocomposites and might also apply to other 2D materials.

Original languageEnglish (US)
Article number011003
JournalNano Futures
Volume1
Issue number1
DOIs
StatePublished - Jun 1 2017

Keywords

  • Bio-inspired Supplementary material for this article is available online
  • Graphene
  • Graphene oxide
  • Hierarchical
  • Mechanical properties
  • Nacre
  • Nanomaterials

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Atomic and Molecular Physics, and Optics
  • Biomedical Engineering
  • Materials Science(all)
  • Electrical and Electronic Engineering

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