TY - JOUR
T1 - Monomeric four-coordinate vanadium(V) oxo complexes containing a labile ligand
T2 - Synthesis and X-ray structural characterization of [(C 23H30O2)V(O)Cl]
AU - Toscano, Paul J.
AU - Schermerhorn, E. James
AU - Dettelbacher, Claudia
AU - MacHerone, Deborah
AU - Zubieta, Jon
PY - 1991
Y1 - 1991
N2 - The reaction of VOCl3 with bulky biphenolic compounds (H 2L) provides dark brown complexes of formula, [V(O)(L)Cl]; X-ray diffraction studies revealed that the complex for which L = 2,2′-CH 2(4-Me,6-ButC6H2O)2 is monomeric in the solid state with approximate tetrahedral geometry about the V atom.
AB - The reaction of VOCl3 with bulky biphenolic compounds (H 2L) provides dark brown complexes of formula, [V(O)(L)Cl]; X-ray diffraction studies revealed that the complex for which L = 2,2′-CH 2(4-Me,6-ButC6H2O)2 is monomeric in the solid state with approximate tetrahedral geometry about the V atom.
UR - http://www.scopus.com/inward/record.url?scp=37049085419&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049085419&partnerID=8YFLogxK
U2 - 10.1039/C39910000933
DO - 10.1039/C39910000933
M3 - Article
AN - SCOPUS:37049085419
SN - 0022-4936
SP - 933
EP - 934
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 14
ER -