Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC5H3N-3-SiMe3)2]

Eric Block; Hyunkyu Kang; Jon Zubieta

doi:10.1016/S0020-1693(00)86815-2

Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC₅H₃N-3-SiMe₃)₂]

Eric Block, Hyunkyu Kang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The oxo-hydrazido (2-) molybdenum(VI) complex [MoO(NNMePh)(2-SC₃H₃N-3-SiMe₃)₂] was prepared either by the reaction of [Mo₂O₃(2-SC₃H₃N-3-SiMe₃)₄] with 1,1-methylphenylhydrazine or by the reaction of [MoCl₂(NNMePh)(2-SC₅H₃N-3-SiMe₃)e] with atmospheric oxygen. The complex exhibits the cis oxo-hydrazido geometry, with the hydrazido (2-) ligand in the linear η¹/x coordination mode. Ctystal data: C₂₃H³²NnOSi₂S₂Mo, triclinic space group P1, a=11.640(2), b=17.206(3), c=7.930(2) \ ̄rA, αa= 102.92(1), β= 99.46(1), γ=93.41(1)°, V= 1519.3(9) Å³, Z= 2, D_cale= 1.30 g cm^-1; structure solution and refinement based on 4746 refiections (Mo Kα, λ = 0.71073 Å; I_o ≥ 3 σ (I_o)) converged at a conventional discrepancy value of 0.043.

Original language	English (US)
Pages (from-to)	227-231
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	181
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)86815-2
State	Published - Mar 15 1991

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(00)86815-2

Cite this

@article{7c9b97fa479f48d882f6ca17c93597de,

title = "Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC5H3N-3-SiMe3)2]",

abstract = "The oxo-hydrazido (2-) molybdenum(VI) complex [MoO(NNMePh)(2-SC3H3N-3-SiMe3)2] was prepared either by the reaction of [Mo2O3(2-SC3H3N-3-SiMe3)4] with 1,1-methylphenylhydrazine or by the reaction of [MoCl2(NNMePh)(2-SC5H3N-3-SiMe3)e] with atmospheric oxygen. The complex exhibits the cis oxo-hydrazido geometry, with the hydrazido (2-) ligand in the linear η1/x coordination mode. Ctystal data: C23H32NnOSi2S2Mo, triclinic space group P1, a=11.640(2), b=17.206(3), c=7.930(2) \{\= }rA, αa= 102.92(1), β= 99.46(1), γ=93.41(1)°, V= 1519.3(9) {\AA}3, Z= 2, Dcale= 1.30 g cm-1; structure solution and refinement based on 4746 refiections (Mo Kα, λ = 0.71073 {\AA}; Io ≥ 3 σ (Io)) converged at a conventional discrepancy value of 0.043.",

author = "Eric Block and Hyunkyu Kang and Jon Zubieta",

year = "1991",

month = mar,

day = "15",

doi = "10.1016/S0020-1693(00)86815-2",

language = "English (US)",

volume = "181",

pages = "227--231",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC5H3N-3-SiMe3)2]

AU - Block, Eric

AU - Kang, Hyunkyu

AU - Zubieta, Jon

PY - 1991/3/15

Y1 - 1991/3/15

N2 - The oxo-hydrazido (2-) molybdenum(VI) complex [MoO(NNMePh)(2-SC3H3N-3-SiMe3)2] was prepared either by the reaction of [Mo2O3(2-SC3H3N-3-SiMe3)4] with 1,1-methylphenylhydrazine or by the reaction of [MoCl2(NNMePh)(2-SC5H3N-3-SiMe3)e] with atmospheric oxygen. The complex exhibits the cis oxo-hydrazido geometry, with the hydrazido (2-) ligand in the linear η1/x coordination mode. Ctystal data: C23H32NnOSi2S2Mo, triclinic space group P1, a=11.640(2), b=17.206(3), c=7.930(2) \ ̄rA, αa= 102.92(1), β= 99.46(1), γ=93.41(1)°, V= 1519.3(9) Å3, Z= 2, Dcale= 1.30 g cm-1; structure solution and refinement based on 4746 refiections (Mo Kα, λ = 0.71073 Å; Io ≥ 3 σ (Io)) converged at a conventional discrepancy value of 0.043.

AB - The oxo-hydrazido (2-) molybdenum(VI) complex [MoO(NNMePh)(2-SC3H3N-3-SiMe3)2] was prepared either by the reaction of [Mo2O3(2-SC3H3N-3-SiMe3)4] with 1,1-methylphenylhydrazine or by the reaction of [MoCl2(NNMePh)(2-SC5H3N-3-SiMe3)e] with atmospheric oxygen. The complex exhibits the cis oxo-hydrazido geometry, with the hydrazido (2-) ligand in the linear η1/x coordination mode. Ctystal data: C23H32NnOSi2S2Mo, triclinic space group P1, a=11.640(2), b=17.206(3), c=7.930(2) \ ̄rA, αa= 102.92(1), β= 99.46(1), γ=93.41(1)°, V= 1519.3(9) Å3, Z= 2, Dcale= 1.30 g cm-1; structure solution and refinement based on 4746 refiections (Mo Kα, λ = 0.71073 Å; Io ≥ 3 σ (Io)) converged at a conventional discrepancy value of 0.043.

UR - http://www.scopus.com/inward/record.url?scp=0039549355&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0039549355&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)86815-2

DO - 10.1016/S0020-1693(00)86815-2

M3 - Article

AN - SCOPUS:0039549355

SN - 0020-1693

VL - 181

SP - 227

EP - 231

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC₅H₃N-3-SiMe₃)₂]

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this