Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3]

Eric Block; Gabriel Ofori-Okai; Hyunkyu Kang; Jon Zubieta

doi:10.1016/S0020-1693(00)80251-0

Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC₆H₅)(2-SC₅H₃N-3-SiMe₃)₃]

Eric Block, Gabriel Ofori-Okai, Hyunkyu Kang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reaction of [Mo₂Cl₄(μ-S₂)(μ-2-SC₅H₃NH-3-SiMe₃)(2-SC₅H₃N-3-SiMe₃)₂] with phenylhydrazine yields [Mo(NNPh)(2-SC₅H₃N-3-SiMe₃)₃] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C₃₀H₄₁N₅Si₃S₃Mo (1): monoclinic space group P2₁n, a = 11.600(2), b = 14.880(3), c = 21.681(3) Å, β = 90.46(1)°, V = 3242.2(12) Å³, Z = 4; 5690 reflections, R = 0.049.

Original language	English (US)
Pages (from-to)	179-184
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	190
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)80251-0
State	Published - Dec 16 1991

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC₆H₅)(2-SC₅H₃N-3-SiMe₃)₃]. / Block, Eric; Ofori-Okai, Gabriel; Kang, Hyunkyu et al.
In: Inorganica Chimica Acta, Vol. 190, No. 2, 16.12.1991, p. 179-184.

Research output: Contribution to journal › Article › peer-review

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title = "Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3]",

abstract = "The reaction of [Mo2Cl4(μ-S2)(μ-2-SC5H3NH-3-SiMe3)(2-SC5H3N-3-SiMe3)2] with phenylhydrazine yields [Mo(NNPh)(2-SC5H3N-3-SiMe3)3] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C30H41N5Si3S3Mo (1): monoclinic space group P21n, a = 11.600(2), b = 14.880(3), c = 21.681(3) {\AA}, β = 90.46(1)°, V = 3242.2(12) {\AA}3, Z = 4; 5690 reflections, R = 0.049.",

author = "Eric Block and Gabriel Ofori-Okai and Hyunkyu Kang and Jon Zubieta",

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doi = "10.1016/S0020-1693(00)80251-0",

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T1 - Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3]

AU - Block, Eric

AU - Ofori-Okai, Gabriel

AU - Kang, Hyunkyu

AU - Zubieta, Jon

PY - 1991/12/16

Y1 - 1991/12/16

N2 - The reaction of [Mo2Cl4(μ-S2)(μ-2-SC5H3NH-3-SiMe3)(2-SC5H3N-3-SiMe3)2] with phenylhydrazine yields [Mo(NNPh)(2-SC5H3N-3-SiMe3)3] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C30H41N5Si3S3Mo (1): monoclinic space group P21n, a = 11.600(2), b = 14.880(3), c = 21.681(3) Å, β = 90.46(1)°, V = 3242.2(12) Å3, Z = 4; 5690 reflections, R = 0.049.

AB - The reaction of [Mo2Cl4(μ-S2)(μ-2-SC5H3NH-3-SiMe3)(2-SC5H3N-3-SiMe3)2] with phenylhydrazine yields [Mo(NNPh)(2-SC5H3N-3-SiMe3)3] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C30H41N5Si3S3Mo (1): monoclinic space group P21n, a = 11.600(2), b = 14.880(3), c = 21.681(3) Å, β = 90.46(1)°, V = 3242.2(12) Å3, Z = 4; 5690 reflections, R = 0.049.

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Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC₆H₅)(2-SC₅H₃N-3-SiMe₃)₃]

Abstract

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