Model complexes for ligand probes of met-hemocyanin and met-tyrosinase derivatives. Structure of a novel 1,1-azido bridged binuclear copper(II) complex

Kenneth D. Karlin, Jon C. Hayes, John P. Hutchinson, Jon A Zubieta

Research output: Contribution to journalArticle

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Abstract

Addition of HX (X = N 3 -, Cl -) to a hydroxy-bridged binuclear copper(II) complex gives X-bridged complexes with an environment analogous to protein binuclear sites; the structure of the azide derivative shows a novel μ-1,1-bridging mode, suggesting this as a possibility in the biological systems.

Original languageEnglish (US)
Pages (from-to)376-378
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
StatePublished - 1983
Externally publishedYes

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ASJC Scopus subject areas

  • Molecular Medicine

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