TY - JOUR
T1 - Metal-organodiphosphonates
T2 - Structural consequences of introducing aromatic tethering groups. the structures of [Cu(phen){HO3P(C 12H8)PO3H}], [{Cu(phen)}2{HO 3P(C12H8)PO3H}] and [Cu(terpy){HO3P(C12H8)PO3H}] and of the bimetallic materials
AU - Deburgomaster, Paul
AU - Darling, Kari
AU - Jones, Stephanie
AU - Zubieta, Jon
PY - 2010/12/15
Y1 - 2010/12/15
N2 - Hydrothermal reactions were used to prepare three copper- organodiphosphonate compounds and two copper-molybdate-organodiphosphonate chains. Compound 1, [Cu(phen){HO3P(C12H 8)PO3H}] is a binuclear Cu(II) compound, while [{Cu(phen)}2{HO3P(C12H8)PO 3H}] (2) is a Cu(I) species with distorted "T" shaped copper coordination geometry. In contrast, [Cu(terpy){HO3P(C 12H8)PO3H}]·1.5H2O (3·1.5H2O) exhibits a zig-zag chain structure. The isomorphous bimetallic diphosphonates, [{Cu(LL)}2MoO2{HO 3P(C12H8)PO3H}3] ·H2O (LL = bpy (4·H2O), phen (5·H2O)) also exhibit chain structures, constructed from {Cu2MoO2} clusters, bridging aromatic diphosphonate ligands, and diphosphonates coordinating to the clusters at one terminus and projecting a second pendant terminus.
AB - Hydrothermal reactions were used to prepare three copper- organodiphosphonate compounds and two copper-molybdate-organodiphosphonate chains. Compound 1, [Cu(phen){HO3P(C12H 8)PO3H}] is a binuclear Cu(II) compound, while [{Cu(phen)}2{HO3P(C12H8)PO 3H}] (2) is a Cu(I) species with distorted "T" shaped copper coordination geometry. In contrast, [Cu(terpy){HO3P(C 12H8)PO3H}]·1.5H2O (3·1.5H2O) exhibits a zig-zag chain structure. The isomorphous bimetallic diphosphonates, [{Cu(LL)}2MoO2{HO 3P(C12H8)PO3H}3] ·H2O (LL = bpy (4·H2O), phen (5·H2O)) also exhibit chain structures, constructed from {Cu2MoO2} clusters, bridging aromatic diphosphonate ligands, and diphosphonates coordinating to the clusters at one terminus and projecting a second pendant terminus.
KW - Bimetallic oxides
KW - Binuclear molecular phosphonates
KW - Copper-organodiphosphonates
KW - Organic-inorganic hybrid materials
UR - http://www.scopus.com/inward/record.url?scp=78649767462&partnerID=8YFLogxK
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U2 - 10.1016/j.ica.2010.07.030
DO - 10.1016/j.ica.2010.07.030
M3 - Article
AN - SCOPUS:78649767462
SN - 0020-1693
VL - 364
SP - 150
EP - 156
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -