TY - JOUR
T1 - Metal-organodiphosphonate chemistry
T2 - Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands
AU - Smith, Tiffany M.
AU - Symester, Diona
AU - Perrin, Kathryn A.
AU - Hudson, Bruce S.
AU - Zubieta, Jon
N1 - Funding Information:
This work was funded by a grant from the National Science Foundation (CHE-0907787).
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2014/2/24
Y1 - 2014/2/24
N2 - Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H2O)(bpy)(1,2-HO3PC 8H8PO3H)] (1), [Zn(bpy)(1,3-HO 3PC8H8PO3H)]·H2O (2·H2O), [M(o-phen)(1,3-HO3PC8H 8PO3H)] (M = Zn (5·H2O), M = Cd (11), and [Zn(tpyprz)(1,2-HO3PC8H8PO3H)] (7), while the phases [M(bpy)2(1,4-H2O3PC 8H8PO3H2)(1,4-HO3PC 8H8PO3H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(bpy)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chain hydrogen-bonded to the {HO3PC 8H8PO3H}2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO 3PC8H8PO3H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO3PC8H8PO 3H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn4(o-phen) 4(1,4-HO3PC8H8PO3) 2(1,4-HO3PC8H8PO3H)] ·3H2O (6·3H2O) and [Cd(o-phen)(1,4-HO 3PC8H8PO3H)] (12).
AB - Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H2O)(bpy)(1,2-HO3PC 8H8PO3H)] (1), [Zn(bpy)(1,3-HO 3PC8H8PO3H)]·H2O (2·H2O), [M(o-phen)(1,3-HO3PC8H 8PO3H)] (M = Zn (5·H2O), M = Cd (11), and [Zn(tpyprz)(1,2-HO3PC8H8PO3H)] (7), while the phases [M(bpy)2(1,4-H2O3PC 8H8PO3H2)(1,4-HO3PC 8H8PO3H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(bpy)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chain hydrogen-bonded to the {HO3PC 8H8PO3H}2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO 3PC8H8PO3H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO3PC8H8PO 3H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn4(o-phen) 4(1,4-HO3PC8H8PO3) 2(1,4-HO3PC8H8PO3H)] ·3H2O (6·3H2O) and [Cd(o-phen)(1,4-HO 3PC8H8PO3H)] (12).
KW - Crystal structures
KW - Low dimensional metal-diphosphonates through ancillary ligand incorporation
KW - Metal-diphosphonate compounds
KW - Zn(II) and Cd(II) coordination polymers
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U2 - 10.1016/j.ica.2013.12.003
DO - 10.1016/j.ica.2013.12.003
M3 - Article
AN - SCOPUS:84892656884
VL - 411
SP - 172
EP - 187
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -