Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands

Tiffany M. Smith; Diona Symester; Kathryn A. Perrin; Bruce S. Hudson; Jon Zubieta

doi:10.1016/j.ica.2013.12.003

Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands

Tiffany M. Smith, Diona Symester, Kathryn A. Perrin, Bruce S. Hudson, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article

5 Scopus citations

Abstract

Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H₂O)(bpy)(1,2-HO₃PC ₈H₈PO₃H)] (1), [Zn(bpy)(1,3-HO ₃PC₈H₈PO₃H)]·H₂O (2·H₂O), [M(o-phen)(1,3-HO₃PC₈H ₈PO₃H)] (M = Zn (5·H₂O), M = Cd (11), and [Zn(tpyprz)(1,2-HO₃PC₈H₈PO₃H)] (7), while the phases [M(bpy)₂(1,4-H₂O₃PC ₈H₈PO₃H₂)(1,4-HO₃PC ₈H₈PO₃H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(_bpy)2(1,4-H ₂O₃PC₈H₈PO₃H ₂)}n2n+ chain hydrogen-bonded to the {HO₃PC ₈H₈PO₃H}^2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO ₃PC₈H₈PO₃H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO₃PC₈H₈PO ₃H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn₄(o-phen) ₄(1,4-HO₃PC₈H₈PO₃) ₂(1,4-HO₃PC₈H₈PO₃H)] ·3H₂O (6·3H₂O) and [Cd(o-phen)(1,4-HO ₃PC₈H₈PO₃H)] (12).

Original language	English (US)
Pages (from-to)	172-187
Number of pages	16
Journal	Inorganica Chimica Acta
Volume	411
DOIs	https://doi.org/10.1016/j.ica.2013.12.003
State	Published - Feb 24 2014

Keywords

Crystal structures
Low dimensional metal-diphosphonates through ancillary ligand incorporation
Metal-diphosphonate compounds
Zn(II) and Cd(II) coordination polymers

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Smith, T. M., Symester, D., Perrin, K. A., Hudson, B. S., & Zubieta, J. (2014). Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands. Inorganica Chimica Acta, 411, 172-187. https://doi.org/10.1016/j.ica.2013.12.003

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title = "Metal-organodiphosphonate chemistry: Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands",

abstract = "Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H2O)(bpy)(1,2-HO3PC 8H8PO3H)] (1), [Zn(bpy)(1,3-HO 3PC8H8PO3H)]·H2O (2·H2O), [M(o-phen)(1,3-HO3PC8H 8PO3H)] (M = Zn (5·H2O), M = Cd (11), and [Zn(tpyprz)(1,2-HO3PC8H8PO3H)] (7), while the phases [M(bpy)2(1,4-H2O3PC 8H8PO3H2)(1,4-HO3PC 8H8PO3H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(bpy)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chain hydrogen-bonded to the {HO3PC 8H8PO3H}2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO 3PC8H8PO3H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO3PC8H8PO 3H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn4(o-phen) 4(1,4-HO3PC8H8PO3) 2(1,4-HO3PC8H8PO3H)] ·3H2O (6·3H2O) and [Cd(o-phen)(1,4-HO 3PC8H8PO3H)] (12).",

keywords = "Crystal structures, Low dimensional metal-diphosphonates through ancillary ligand incorporation, Metal-diphosphonate compounds, Zn(II) and Cd(II) coordination polymers",

author = "Smith, {Tiffany M.} and Diona Symester and Perrin, {Kathryn A.} and Hudson, {Bruce S.} and Jon Zubieta",

year = "2014",

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day = "24",

doi = "10.1016/j.ica.2013.12.003",

language = "English (US)",

volume = "411",

pages = "172--187",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

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T2 - Hydrothermal syntheses and structures of Zn(II) and Cd(II) coordination polymers with xylyldiphosphonate ligands

AU - Smith, Tiffany M.

AU - Symester, Diona

AU - Perrin, Kathryn A.

AU - Hudson, Bruce S.

AU - Zubieta, Jon

PY - 2014/2/24

Y1 - 2014/2/24

N2 - Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H2O)(bpy)(1,2-HO3PC 8H8PO3H)] (1), [Zn(bpy)(1,3-HO 3PC8H8PO3H)]·H2O (2·H2O), [M(o-phen)(1,3-HO3PC8H 8PO3H)] (M = Zn (5·H2O), M = Cd (11), and [Zn(tpyprz)(1,2-HO3PC8H8PO3H)] (7), while the phases [M(bpy)2(1,4-H2O3PC 8H8PO3H2)(1,4-HO3PC 8H8PO3H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(bpy)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chain hydrogen-bonded to the {HO3PC 8H8PO3H}2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO 3PC8H8PO3H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO3PC8H8PO 3H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn4(o-phen) 4(1,4-HO3PC8H8PO3) 2(1,4-HO3PC8H8PO3H)] ·3H2O (6·3H2O) and [Cd(o-phen)(1,4-HO 3PC8H8PO3H)] (12).

AB - Hydrothermal reactions of zinc(II) acetate dihydrate or cadmium(II) nitrate tetrahydrate with xylyldiphosphonic acid isomers in the presence of an organonitrogen chelating ancillary ligand provided a series of materials of the (M(II)-organonitrogen chelate)/xylyldiphosphonate family. One-dimensional structures were observed for [Zn(H2O)(bpy)(1,2-HO3PC 8H8PO3H)] (1), [Zn(bpy)(1,3-HO 3PC8H8PO3H)]·H2O (2·H2O), [M(o-phen)(1,3-HO3PC8H 8PO3H)] (M = Zn (5·H2O), M = Cd (11), and [Zn(tpyprz)(1,2-HO3PC8H8PO3H)] (7), while the phases [M(bpy)2(1,4-H2O3PC 8H8PO3H2)(1,4-HO3PC 8H8PO3H)] (M = Zn (3) and Cd(9)) exhibited virtual layered structures constructed from {M(bpy)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chain hydrogen-bonded to the {HO3PC 8H8PO3H}2- charge compensating anions. The two-dimensional structures are represented by [M(o-phen)(1,2-HO 3PC8H8PO3H)] (M = Zn (4) and Cd (10)) and [Cd(bpy)(1,3-HO3PC8H8PO 3H)] (8). Expansion into three-dimensions occurs only with the spatially extended 1,4-xylyldiphosphonate ligand in [Zn4(o-phen) 4(1,4-HO3PC8H8PO3) 2(1,4-HO3PC8H8PO3H)] ·3H2O (6·3H2O) and [Cd(o-phen)(1,4-HO 3PC8H8PO3H)] (12).

KW - Crystal structures

KW - Low dimensional metal-diphosphonates through ancillary ligand incorporation

KW - Metal-diphosphonate compounds

KW - Zn(II) and Cd(II) coordination polymers

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JO - Inorganica Chimica Acta

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