@article{5fc0a282c6674582aa8bc7f2e2fcd43c,
title = "Metal Free Amino-Oxidation of Electron Rich Alkenes Mediated by an Oxoammonium Salt",
abstract = "4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium tetrafluoroborate (Bobbitt's salt) effectively activates electron rich alkenes and promotes the addition of anilines. This transformation provides a direct, transition metal free method for amino-oxidation of alkenes under mild conditions. The relative stereochemistry of the amino-oxidation is influenced by solvent effects, with both the syn and anti amino-oxidation products being accessible from identical starting materials.",
keywords = "alkenes, amination, oxidation, oxoammonium, regioselective",
author = "Millimaci, {Alexandra M.} and Meador, {Rowan I.L.} and Dampf, {Sara J.} and Chisholm, {John D.}",
note = "Funding Information: NMR spectra were obtained using instrumentation acquired with the assistance of the National Science Foundation (CHE‐1229345). R.I.L.M. was partially supported by a GAANN fellowship award from the U.S. Dept. of Education (P200 A160193). Funding Information: NMR spectra were obtained using instrumentation acquired with the assistance of the National Science Foundation (CHE-1229345). R.I.L.M. was partially supported by a GAANN fellowship award from the U.S. Dept. of Education (P200 A160193). Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH.",
year = "2021",
month = may,
doi = "10.1002/ijch.202000080",
language = "English (US)",
volume = "61",
pages = "322--326",
journal = "Israel Journal of Chemistry",
issn = "0021-2148",
publisher = "Wiley-VCH Verlag",
number = "5-6",
}