Matrix-Isolation Decay Kinetics of Triplet Cyclobutanediyls. Observation of Both Arrhenius Behavior and Heavy-Atom Tunneling in C—C Bond-Forming Reactions

Keyphrases

• Heavy-atom Tunneling 100%
• Bond-forming Reactions 100%
• Arrhenius Behavior 100%
• Matrix Isolation 100%
• Ring-closure Reactions 50%
• Activation Energy Distribution 50%
• Singlet Biradical 50%
• Dispersive Kinetics 50%
• Isolation Condition 50%

Chemistry

• Matrix Isolation 100%
• Cyclization Reaction 50%