Linear finite "mers" - Homoleptic polynuclear heavy alkaline earth metal pyrazolates

Julia Hitzbleck, Glen B. Deacon, Karin Ruhlandt

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

The bigger the better: Increasing metal size seems to be the determining factor in the formation of an unprecedented series of homoleptic linear pyrazolates of the heavy alkaline-earth metals (Ca, Sr, Ba, see picture, Ba = green, N = blue, C = black), with the formation of trinuclear calcium, tetranuclear strontium, and hexanuclear barium derivatives. The linear oligomers display a noteworthy array of metal-ligand bonds.

Original languageEnglish (US)
Pages (from-to)5218-5220
Number of pages3
JournalAngewandte Chemie (International Edition in English)
Volume43
Issue number39
DOIs
StatePublished - Oct 4 2004

Fingerprint

Alkaline Earth Metals
Alkaline earth metals
Heavy metals
Metals
Strontium
Barium
Oligomers
Calcium
Ligands
Derivatives

Keywords

  • Alkaline-earth metals
  • Coordination modes
  • N ligands
  • Solvolysis
  • Structure elucidation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Linear finite "mers" - Homoleptic polynuclear heavy alkaline earth metal pyrazolates. / Hitzbleck, Julia; Deacon, Glen B.; Ruhlandt, Karin.

In: Angewandte Chemie (International Edition in English), Vol. 43, No. 39, 04.10.2004, p. 5218-5220.

Research output: Contribution to journalArticle

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