TY - JOUR
T1 - Linear finite "mers" - Homoleptic polynuclear heavy alkaline earth metal pyrazolates
AU - Hitzbleck, Julia
AU - Deacon, Glen B.
AU - Ruhlandt-Senge, Karin
PY - 2004/10/4
Y1 - 2004/10/4
N2 - The bigger the better: Increasing metal size seems to be the determining factor in the formation of an unprecedented series of homoleptic linear pyrazolates of the heavy alkaline-earth metals (Ca, Sr, Ba, see picture, Ba = green, N = blue, C = black), with the formation of trinuclear calcium, tetranuclear strontium, and hexanuclear barium derivatives. The linear oligomers display a noteworthy array of metal-ligand bonds.
AB - The bigger the better: Increasing metal size seems to be the determining factor in the formation of an unprecedented series of homoleptic linear pyrazolates of the heavy alkaline-earth metals (Ca, Sr, Ba, see picture, Ba = green, N = blue, C = black), with the formation of trinuclear calcium, tetranuclear strontium, and hexanuclear barium derivatives. The linear oligomers display a noteworthy array of metal-ligand bonds.
KW - Alkaline-earth metals
KW - Coordination modes
KW - N ligands
KW - Solvolysis
KW - Structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=6044274717&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=6044274717&partnerID=8YFLogxK
U2 - 10.1002/anie.200460628
DO - 10.1002/anie.200460628
M3 - Article
C2 - 15455420
AN - SCOPUS:6044274717
SN - 1433-7851
VL - 43
SP - 5218
EP - 5220
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 39
ER -