Ligand and coligand effects on ion association in magnesium amides

Ana Torvisco, Karin Ruhlandt

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We report here the examination of the effect of ligand bulk and coligand influence on ion association in a family of magnesium amides. Use of the sparsely employed, sterically demanding coligand HMPA (hexamethylphosphoramide, O=P(N(Me)2)3, in conjunction with four different silylamides [N(SiMe3)(R)]- (R = SiMe3, C 6H5 (Ph), 2,4,6-MesC6H2 (Mes), 2,6-i-Pr2C6H3 (Dipp)) provides unique insight into factors governing ion association. To this effect, we report three contact molecules, along with one example of a rare ion-association state with one amido group metal-bound, whereas the other is unassociated.

Original languageEnglish (US)
Pages (from-to)986-991
Number of pages6
JournalOrganometallics
Volume30
Issue number5
DOIs
StatePublished - Mar 14 2011

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Amides
Magnesium
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Metals
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metals
molecules

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Ligand and coligand effects on ion association in magnesium amides. / Torvisco, Ana; Ruhlandt, Karin.

In: Organometallics, Vol. 30, No. 5, 14.03.2011, p. 986-991.

Research output: Contribution to journalArticle

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