Investigations of the V/O/RAsO32- system: Solvothermal synthesis and crystal and molecular structure of [(V 2O3)(Ph6As6O14)]

José Salta, Yuan Da Chang, Jon Zubieta

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

The reaction of PPh4[VO2Cl2] with PhAsO3H2 in acetonitrile for 36 h at 100 °C and autogenous pressure yields [(V2O3)(Ph6As 6O14)], an unusual cluster with a {V2O 3}4+ core straddled by the hexadentate ligand {Ph 6As6O14}4-, which forms via thermally induced condensation of PhAsO3H2 groups.

Original languageEnglish (US)
Pages (from-to)1039-1040
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - Dec 1 1994

ASJC Scopus subject areas

  • Molecular Medicine

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