Investigations of the copper bromide-2,2′-dipyridyl system: (see abstract)

Robert P. Hammond; Michael Cavaluzzi; Robert C. Haushalter; Jon A. Zubieta

doi:10.1021/ic980997v

Investigations of the copper bromide-2,2′-dipyridyl system: (see abstract)

Robert P. Hammond, Michael Cavaluzzi, Robert C. Haushalter, Jon A. Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

The hydrothermal reactions of CuBr₂, CuBr, and 2,2′-dipyridyl have resulted in the synthesis of three new compounds. Cu₃Br₄C₁₀H₈N₂) ₂ (1) is a molecular phase; CuBr₂(C₁₀H₈N₂) (2) is a one-dimensional chain structure; and [Cu₂(OH)₂(C₁₀H₈N₂) ₂][Cu₄Br₆] (3) crystallizes in a two-dimensional sheet structure. All three compounds were characterized by single-crystal X-ray diffraction. Crystal data for 1, triclinic, space group P1̄ (No. 2) with a = 10.604(2) Å, b = 11.642(2) Ä, c = 11.688(2) Ä, α = 61.965(5)°, β = 68.965(5)°, γ = 69.523(5)°, Z = 2; 2, monoclinic, space group C2/c (No. 15) with a = 16.766(4) Å, b = 9.287(2) Å, c = 7.392(2) Å, β = 110.536-(6)°, Z = 4; 3, monoclinic, space group P2₁/n (No. 14) with a = 10.907(3) Å, b = 6.0677(13) Å, c = 21.620(5) Å, β = 90.542(4)°, Z = 4.

Original language	English (US)
Pages (from-to)	1288-1292
Number of pages	5
Journal	Inorganic Chemistry
Volume	38
Issue number	6
DOIs	https://doi.org/10.1021/ic980997v
State	Published - 1999

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic980997v

Cite this

@article{6300ba26cd894f9291b6a26096345140,

title = "Investigations of the copper bromide-2,2′-dipyridyl system: (see abstract)",

abstract = "The hydrothermal reactions of CuBr2, CuBr, and 2,2′-dipyridyl have resulted in the synthesis of three new compounds. Cu3Br4C10H8N2) 2 (1) is a molecular phase; CuBr2(C10H8N2) (2) is a one-dimensional chain structure; and [Cu2(OH)2(C10H8N2) 2][Cu4Br6] (3) crystallizes in a two-dimensional sheet structure. All three compounds were characterized by single-crystal X-ray diffraction. Crystal data for 1, triclinic, space group P{\=1} (No. 2) with a = 10.604(2) {\AA}, b = 11.642(2) {\"A}, c = 11.688(2) {\"A}, α = 61.965(5)°, β = 68.965(5)°, γ = 69.523(5)°, Z = 2; 2, monoclinic, space group C2/c (No. 15) with a = 16.766(4) {\AA}, b = 9.287(2) {\AA}, c = 7.392(2) {\AA}, β = 110.536-(6)°, Z = 4; 3, monoclinic, space group P21/n (No. 14) with a = 10.907(3) {\AA}, b = 6.0677(13) {\AA}, c = 21.620(5) {\AA}, β = 90.542(4)°, Z = 4.",

author = "Hammond, {Robert P.} and Michael Cavaluzzi and Haushalter, {Robert C.} and Zubieta, {Jon A.}",

year = "1999",

doi = "10.1021/ic980997v",

language = "English (US)",

volume = "38",

pages = "1288--1292",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Investigations of the copper bromide-2,2′-dipyridyl system

T2 - (see abstract)

AU - Hammond, Robert P.

AU - Cavaluzzi, Michael

AU - Haushalter, Robert C.

AU - Zubieta, Jon A.

PY - 1999

Y1 - 1999

N2 - The hydrothermal reactions of CuBr2, CuBr, and 2,2′-dipyridyl have resulted in the synthesis of three new compounds. Cu3Br4C10H8N2) 2 (1) is a molecular phase; CuBr2(C10H8N2) (2) is a one-dimensional chain structure; and [Cu2(OH)2(C10H8N2) 2][Cu4Br6] (3) crystallizes in a two-dimensional sheet structure. All three compounds were characterized by single-crystal X-ray diffraction. Crystal data for 1, triclinic, space group P1̄ (No. 2) with a = 10.604(2) Å, b = 11.642(2) Ä, c = 11.688(2) Ä, α = 61.965(5)°, β = 68.965(5)°, γ = 69.523(5)°, Z = 2; 2, monoclinic, space group C2/c (No. 15) with a = 16.766(4) Å, b = 9.287(2) Å, c = 7.392(2) Å, β = 110.536-(6)°, Z = 4; 3, monoclinic, space group P21/n (No. 14) with a = 10.907(3) Å, b = 6.0677(13) Å, c = 21.620(5) Å, β = 90.542(4)°, Z = 4.

AB - The hydrothermal reactions of CuBr2, CuBr, and 2,2′-dipyridyl have resulted in the synthesis of three new compounds. Cu3Br4C10H8N2) 2 (1) is a molecular phase; CuBr2(C10H8N2) (2) is a one-dimensional chain structure; and [Cu2(OH)2(C10H8N2) 2][Cu4Br6] (3) crystallizes in a two-dimensional sheet structure. All three compounds were characterized by single-crystal X-ray diffraction. Crystal data for 1, triclinic, space group P1̄ (No. 2) with a = 10.604(2) Å, b = 11.642(2) Ä, c = 11.688(2) Ä, α = 61.965(5)°, β = 68.965(5)°, γ = 69.523(5)°, Z = 2; 2, monoclinic, space group C2/c (No. 15) with a = 16.766(4) Å, b = 9.287(2) Å, c = 7.392(2) Å, β = 110.536-(6)°, Z = 4; 3, monoclinic, space group P21/n (No. 14) with a = 10.907(3) Å, b = 6.0677(13) Å, c = 21.620(5) Å, β = 90.542(4)°, Z = 4.

UR - http://www.scopus.com/inward/record.url?scp=0000107146&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000107146&partnerID=8YFLogxK

U2 - 10.1021/ic980997v

DO - 10.1021/ic980997v

M3 - Article

AN - SCOPUS:0000107146

SN - 0020-1669

VL - 38

SP - 1288

EP - 1292

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Investigations of the copper bromide-2,2′-dipyridyl system: (see abstract)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this