TY - JOUR
T1 - Investigations of organic-inorganic hybrid materials
T2 - Ligand influences on the structures of copper-vanadium oxide materials
AU - Smith, Tiffany M.
AU - Freund, Steven R.
AU - Lau, Adam
AU - Varges, Jose
AU - Spinu, Leonard
AU - Zubieta, Jon
N1 - Funding Information:
This work was funded by a grant from the National Science Foundation (CHE-0907787). A.L. thanks the NSF-REU program for Summer support.
PY - 2014/4/1
Y1 - 2014/4/1
N2 - Hydrothermal synthesis was exploited to provide three compounds of the VxOy/Cu/imine family. Compound 1, [{Cu2(2, 2′-dpam)4}V4O12] is molecular, while [{Cu2(OH)(o-phen)2}V3O9] (2) and [{Cu2(4,4′-bpy)3(H2O)2}V 4O12]·5H2O (3·5H2O) are one-dimensional and three-dimensional, respectively. The copper-imine components are shown to be critical structural determinants that assume charge-compensating and space-filling roles, as well as providing ligand geometric and steric constrains, as well as flexible metal coordination geometry.
AB - Hydrothermal synthesis was exploited to provide three compounds of the VxOy/Cu/imine family. Compound 1, [{Cu2(2, 2′-dpam)4}V4O12] is molecular, while [{Cu2(OH)(o-phen)2}V3O9] (2) and [{Cu2(4,4′-bpy)3(H2O)2}V 4O12]·5H2O (3·5H2O) are one-dimensional and three-dimensional, respectively. The copper-imine components are shown to be critical structural determinants that assume charge-compensating and space-filling roles, as well as providing ligand geometric and steric constrains, as well as flexible metal coordination geometry.
KW - Bimetallic oxide materials
KW - Copper vanadates
KW - Imine ligands
KW - Organic-inorganic hybrid materials
KW - X-ray structures
UR - http://www.scopus.com/inward/record.url?scp=84897712632&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84897712632&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2014.01.022
DO - 10.1016/j.ica.2014.01.022
M3 - Article
AN - SCOPUS:84897712632
SN - 0020-1693
VL - 414
SP - 91
EP - 96
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -