TY - JOUR
T1 - Investigations into the Targeted Design of Solids
T2 - Hydrothermal Synthesis and Structures of One‐, Two‐, and Three‐Dimensional Phases of the Oxovanadium–Organodiphosphonate System
AU - Soghomonian, Victoria
AU - Chen, Qin
AU - Haushalter, Robert C.
AU - Zubieta, Jon
PY - 1995/2/3
Y1 - 1995/2/3
N2 - Depending on the tether length of the diphosphonate group, hydrothermal reactions of VCl4 with diphosphonic acids of the class (H2O3P)(CH2)n(PO3H2) in the presence of templating organic cations yield one‐, two‐, and three‐dimensional framework structures of the V‐O‐RPO 32− system. The picture shows a section of the three‐dimensional framework of [H3N(CH2)2NH3][(VO)4(OH)2(H2O)2{O3P(CH2)3PO3}2]·4H2O. (Figure Presented.)
AB - Depending on the tether length of the diphosphonate group, hydrothermal reactions of VCl4 with diphosphonic acids of the class (H2O3P)(CH2)n(PO3H2) in the presence of templating organic cations yield one‐, two‐, and three‐dimensional framework structures of the V‐O‐RPO 32− system. The picture shows a section of the three‐dimensional framework of [H3N(CH2)2NH3][(VO)4(OH)2(H2O)2{O3P(CH2)3PO3}2]·4H2O. (Figure Presented.)
KW - hydrothermal synthesis
KW - polyoxometalates
KW - solid‐state structures
KW - vanadium compounds
UR - http://www.scopus.com/inward/record.url?scp=33748226299&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33748226299&partnerID=8YFLogxK
U2 - 10.1002/anie.199502231
DO - 10.1002/anie.199502231
M3 - Article
AN - SCOPUS:33748226299
SN - 0570-0833
VL - 34
SP - 223
EP - 226
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 2
ER -