Investigations into the Targeted Design of Solids: Hydrothermal Synthesis and Structures of One‐, Two‐, and Three‐Dimensional Phases of the Oxovanadium–Organodiphosphonate System

Victoria Soghomonian, Qin Chen, Robert C. Haushalter, Jon Zubieta

Research output: Contribution to journalArticle

190 Scopus citations

Abstract

Depending on the tether length of the diphosphonate group, hydrothermal reactions of VCl4 with diphosphonic acids of the class (H2O3P)(CH2)n(PO3H2) in the presence of templating organic cations yield one‐, two‐, and three‐dimensional framework structures of the V‐O‐RPO 32− system. The picture shows a section of the three‐dimensional framework of [H3N(CH2)2NH3][(VO)4(OH)2(H2O)2{O3P(CH2)3PO3}2]·4H2O. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)223-226
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume34
Issue number2
DOIs
StatePublished - Feb 3 1995

Keywords

  • hydrothermal synthesis
  • polyoxometalates
  • solid‐state structures
  • vanadium compounds

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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