Investigation of the terahertz vibrational modes of ZIF-8 and ZIF-90 with terahertz time-domain spectroscopy

Nicholas Y. Tan, Michael T. Ruggiero, Claudia Orellana, Tian Tian, Andrew D. Bond, Timothy M. Korter, David Fairen-Jimenez, J. Axel Zeitler

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Scopus citations

Abstract

The terahertz spectra of ZIF-8 and ZIF-90 were acquired with terahertz time-domain spectroscopy (THz-TDS). Ab initio quantum mechanical calculations yield in spectra that match well with the experimental results and indicate that swing motions in these ZIFs may lie within the terahertz region. Variable temperature THz-TDS measurements on ZIF-90 suggest that the technique is sensitive to host-guest interactions, which can be used to study them in the future.

Original languageEnglish (US)
Title of host publicationIRMMW-THz 2015 - 40th International Conference on Infrared, Millimeter, and Terahertz Waves
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)9781479982721
DOIs
StatePublished - Nov 11 2015
Event40th International Conference on Infrared, Millimeter, and Terahertz Waves, IRMMW-THz 2015 - Hong Kong, China
Duration: Aug 23 2015Aug 28 2015

Publication series

NameIRMMW-THz 2015 - 40th International Conference on Infrared, Millimeter, and Terahertz Waves

Other

Other40th International Conference on Infrared, Millimeter, and Terahertz Waves, IRMMW-THz 2015
CountryChina
CityHong Kong
Period8/23/158/28/15

ASJC Scopus subject areas

  • Radiation
  • Computer Networks and Communications

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    Tan, N. Y., Ruggiero, M. T., Orellana, C., Tian, T., Bond, A. D., Korter, T. M., Fairen-Jimenez, D., & Zeitler, J. A. (2015). Investigation of the terahertz vibrational modes of ZIF-8 and ZIF-90 with terahertz time-domain spectroscopy. In IRMMW-THz 2015 - 40th International Conference on Infrared, Millimeter, and Terahertz Waves [7327716] (IRMMW-THz 2015 - 40th International Conference on Infrared, Millimeter, and Terahertz Waves). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/IRMMW-THz.2015.7327716