Improved Performance of Carbon Electrode Perovskite Solar Cells Using Urea Treatment in Two-Step Processing

Tingting Xu, Xuelin Sun, Weiwei Cao, Xiulan Qin, Ashim Gurung, Shaoshen Lv, Yonghua Chen, Lixin Chen, Wei Huang, Qiquan Qiao

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Perovskite solar cell has made a steady research progress with superior photovoltaic power conversion efficiency (PCE) over 25%. The quality of perovskite film is a key factor affecting device efficiency. Lewis bases such as urea, DMSO and thiourea etc. have been applied in perovskite precursor solutions for one step processing to effectively control the film morphology. Herein, we report urea treatment in a two-step processing for obtaining high quality methylammonium lead triiodide perovskite (CH3NH3PbI3) film, which is accomplished by immersing the PbI2 film into the mixture solution of urea/methylammonium iodide (MAI). The optimized urea concentration in the MAI solution is 0.4 mg/mL, leading to larger-sized and better crystalline perovskite grains than that without urea additive. The main function of the urea additive is the formation of the adduct MAI⋅PbI2⋅O=C(NH2)2, retarding the crystallization process of the perovskite film. The steady-state and time-resolved photoluminescence measurements revealed that perovskite CH3NH3PbI3 grown using optimized concentration of urea has prolonged carrier lifetime and reduced carrier recombination. Finally, the carbon-based perovskite solar cells fabricated from the optimal urea concentration of 0.4 mg/mL achieved the enhanced photovoltaic performance with the highest PCE of 13.10% and an average value of 11.34%, in comparison to devices without urea treatment exhibiting an average PCE of only 8.67%.

Original languageEnglish (US)
Pages (from-to)806-815
Number of pages10
JournalChemNanoMat
Volume6
Issue number5
DOIs
StatePublished - May 1 2020
Externally publishedYes

Keywords

  • Lewis base additive
  • carbon-based perovskite solar cell
  • grain size
  • urea

ASJC Scopus subject areas

  • Biomaterials
  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Improved Performance of Carbon Electrode Perovskite Solar Cells Using Urea Treatment in Two-Step Processing'. Together they form a unique fingerprint.

Cite this