TY - JOUR
T1 - Hydrothermal synthesis, solid state structure, and thermal properties of a family of isomorphous 1-D coordination polymers aggregated by extensive hydrogen bonding
T2 - {[M(3,3′-bpy)(H2O)4](SO 4)·2H2O} (M = Co, Ni, Zn)
AU - LaDuca, Robert L.
AU - Desciak, Matthew P.
AU - Rarig, Randy S.
AU - Zubieta, Jon A.
PY - 2006
Y1 - 2006
N2 - Hydrothermal synthesis has afforded a family of new coordination polymers incorporating 3,3′-bipyridine (3,3′-bpy), {[M(3,3′-bpy)(H 2O)4](SO4)·2H2O} (M = Co, Ni, Zn). The crystal structures revealed 1-D undulating cationic ribbons of formulation {[M(3,3′-bpy)(H2O)4]}n 2n+ with both unligated charge-balancing sulfate anions and water molecules of crystallization entrapped by hydrogen bonding. The 1-D ribbons run along the (101) crystal direction and further aggregate via extensive hydrogen bonding patterns. Thermal decomposition data were consistent with step-wise loss of water molecules of crystallization and aquo ligands followed by decomposition due to ligand removal.
AB - Hydrothermal synthesis has afforded a family of new coordination polymers incorporating 3,3′-bipyridine (3,3′-bpy), {[M(3,3′-bpy)(H 2O)4](SO4)·2H2O} (M = Co, Ni, Zn). The crystal structures revealed 1-D undulating cationic ribbons of formulation {[M(3,3′-bpy)(H2O)4]}n 2n+ with both unligated charge-balancing sulfate anions and water molecules of crystallization entrapped by hydrogen bonding. The 1-D ribbons run along the (101) crystal direction and further aggregate via extensive hydrogen bonding patterns. Thermal decomposition data were consistent with step-wise loss of water molecules of crystallization and aquo ligands followed by decomposition due to ligand removal.
KW - Coordination chemistry
KW - Hydrogen bonds
KW - Hydrothermal synthesis
KW - Inorganic-organic hybrid composites
KW - Metal sulfate
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U2 - 10.1002/zaac.200500386
DO - 10.1002/zaac.200500386
M3 - Article
AN - SCOPUS:33144472825
SN - 0044-2313
VL - 632
SP - 449
EP - 453
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 3
ER -