Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]

Robert L. Laduca; Matthew Desciak; Matthew Laskoski; Randy S. Rarig; Jon Zubieta

doi:10.1039/b001419m

Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

Robert L. Laduca, Matthew Desciak, Matthew Laskoski, Randy S. Rarig, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

The hydrothermal chemistry of the Ni(II)/molybdate/ 3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)] 2 is isolated.

Original language	English (US)
Pages (from-to)	2255-2257
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/b001419m
State	Published - 2000
Externally published	Yes

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General Chemistry

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Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]. / Laduca, Robert L.; Desciak, Matthew; Laskoski, Matthew et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 14, 2000, p. 2255-2257.

Research output: Contribution to journal › Article › peer-review

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title = "Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]",

abstract = "The hydrothermal chemistry of the Ni(II)/molybdate/ 3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)2}2Mo4O14] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo4O13(OH)] 2 is isolated.",

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AU - Laduca, Robert L.

AU - Desciak, Matthew

AU - Laskoski, Matthew

AU - Rarig, Randy S.

AU - Zubieta, Jon

PY - 2000

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AB - The hydrothermal chemistry of the Ni(II)/molybdate/ 3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)2}2Mo4O14] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo4O13(OH)] 2 is isolated.

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Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

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