Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family: The structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]

Robert L. Laduca, Matthew Desciak, Matthew Laskoski, Randy S. Rarig, Jon A Zubieta

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Abstract

The hydrothermal chemistry of the Ni(II)/molybdate/ 3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)2}2Mo4O14] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo4O13(OH)] 2 is isolated.

Original languageEnglish (US)
Pages (from-to)2255-2257
Number of pages3
JournalJournal of the Chemical Society - Dalton Transactions
Issue number14
DOIs
StatePublished - 2000
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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