Hydrothermal synthesis of organic - Inorganic hybrid materials: Network structures of the bimetallic oxides [M(Hdpa)2V4O12] (M = Co, Ni, dpa = 4,4′-dipyridylamine)

R. L. LaDuca, R. S. Rarig, Jon A Zubieta

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Abstract

The hydrothermal reactions of MCl2·6H2O (M = Co, Ni) NaVO3, 4,4′-dipyridylamine (dpa), and H2O yield materials of the type [M(Hdpa)2V4O12] (M = Co (1), Ni (2)). The two-dimensional structures of 1 and 2 are constructed from bimetallic oxide networks {MV4O12}n2n- with monodentate Hdpa† projecting the protonated ring into the interlamellar region. The oxide network may be described as ruffled chains of corner-sharing {VO4} tetrahedra linked by {NiO4N2} octahedra into the two-dimensional assembly. Crystal data: C10H10Co0.5N3O 6V2 (1), monoclinic P21/c, a = 10.388(1) Å, b = 7.6749(7) Å, c = 16.702(2) Å, β = 102.516(1)°, Z = 4. C10H10N3- Ni0.5O6V2 (2), monoclinic, P21/c, c = 10.3815(2) Å, b = 7.7044(2) Å, c = 16.6638(4) Å, β = 102.573(1)° Z = 4.

Original languageEnglish (US)
Pages (from-to)607-612
Number of pages6
JournalInorganic Chemistry
Volume40
Issue number4
DOIs
StatePublished - Feb 12 2001

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ASJC Scopus subject areas

  • Inorganic Chemistry

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