Hydrothermal synthesis and structure of [VO2(terpy)][(VO2)2(PO4)], a novel network material (terpy = 2,2′:6′,2″ terpyridine)

Robert C. Finn, Jon Zubieta

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

The hydrothermal reaction of Na3VO4, H3PO4, 2,2′:6′,2″-terpyridine and water in the mole ratio 2.73: 10.1: 1.00: 1220 provided orange crystals of [VO2(terpy)][(VO2)2(PO4)] in good yield. The structure consists of {(VO2)2(PO4)}n-n layers with charge-compensating {VO2(terpy)}1+ molecular cations occupying the interlamellar regions. The layer structure consists of a network constructed from chains of corner-sharing {VO5} square pyramids, linked through {PO4}3- tetrahedra. The layer is characterized by cyclic eight polyhedra connects producing sixteen member rings {V6P2O8} which fuse to produce the two-dimensional connectivity. Crystal data: C15H11N3O10PV3, monoclinic, C2/c, a = 12.315(1), b = 10.835(1), c = 29.181(3) Å, β = 101.618(2)°, V = 3814.2(6) Å3, Z = 8, Dcalc = 2.010 g cm-3.

Original languageEnglish (US)
Pages (from-to)845-849
Number of pages5
JournalSolid State Sciences
Volume4
Issue number6
DOIs
StatePublished - Jun 20 2002

Keywords

  • Hydrothermal synthesis
  • Organic-inorganic hybrid material
  • Two-dimensional phosphate
  • Vanadium phosphate

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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