TY - JOUR
T1 - Hydrothermal synthesis and structure of a two-dimensional Fe(III)-organodiphosphonate compound, [Fe(O3PCH2C6H4CH2PO3H)(H2O)], and an Expansion of the Harris Notation
AU - Lopez, Valerie
AU - Minichelli, Julian
AU - Case, Derek
AU - Ruhlandt, Karin
AU - Doyle, Robert P.
AU - Zubieta, Jon
PY - 2020/6/1
Y1 - 2020/6/1
N2 - The hydrothermal reaction of FeCl2·4H2O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C8H8P2O6H4), and triethylamine produced [Fe(o-C8H8P2O6H)(H2O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O6 octahedra linked through RPO3 tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.111213/2.11140] bonding mode, according to a modified Harris notation.
AB - The hydrothermal reaction of FeCl2·4H2O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C8H8P2O6H4), and triethylamine produced [Fe(o-C8H8P2O6H)(H2O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O6 octahedra linked through RPO3 tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.111213/2.11140] bonding mode, according to a modified Harris notation.
KW - Coordination polymer
KW - Iron(III)
KW - Organodiphosphonate
KW - Two-dimensional structure
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U2 - 10.1016/j.ica.2020.119518
DO - 10.1016/j.ica.2020.119518
M3 - Article
AN - SCOPUS:85079855780
SN - 0020-1693
VL - 506
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
M1 - 119518
ER -