Hydrothermal synthesis and structure of a two-dimensional Fe(III)-organodiphosphonate compound, [Fe(O3PCH2C6H4CH2PO3H)(H2O)], and an Expansion of the Harris Notation

Valerie Lopez; Julian Minichelli; Derek Case; Karin Ruhlandt; Robert P. Doyle; Jon Zubieta

doi:10.1016/j.ica.2020.119518

Hydrothermal synthesis and structure of a two-dimensional Fe(III)-organodiphosphonate compound, [Fe(O₃PCH₂C₆H₄CH₂PO₃H)(H₂O)], and an Expansion of the Harris Notation

Valerie Lopez, Julian Minichelli, Derek Case, Karin Ruhlandt, Robert P. Doyle, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The hydrothermal reaction of FeCl₂·4H₂O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C₈H₈P₂O₆H₄), and triethylamine produced [Fe(o-C₈H₈P₂O₆H)(H₂O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O₆ octahedra linked through RPO₃ tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.1₁1₂1₃/2.1₁1₄0] bonding mode, according to a modified Harris notation.

Original language	English (US)
Article number	119518
Journal	Inorganica Chimica Acta
Volume	506
DOIs	https://doi.org/10.1016/j.ica.2020.119518
State	Published - Jun 1 2020

Keywords

Coordination polymer
Iron(III)
Organodiphosphonate
Two-dimensional structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2020.119518

Cite this

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title = "Hydrothermal synthesis and structure of a two-dimensional Fe(III)-organodiphosphonate compound, [Fe(O3PCH2C6H4CH2PO3H)(H2O)], and an Expansion of the Harris Notation",

abstract = "The hydrothermal reaction of FeCl2·4H2O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C8H8P2O6H4), and triethylamine produced [Fe(o-C8H8P2O6H)(H2O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O6 octahedra linked through RPO3 tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.111213/2.11140] bonding mode, according to a modified Harris notation.",

keywords = "Coordination polymer, Iron(III), Organodiphosphonate, Two-dimensional structure",

author = "Valerie Lopez and Julian Minichelli and Derek Case and Karin Ruhlandt and Doyle, {Robert P.} and Jon Zubieta",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = jun,

day = "1",

doi = "10.1016/j.ica.2020.119518",

language = "English (US)",

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journal = "Inorganica Chimica Acta",

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T1 - Hydrothermal synthesis and structure of a two-dimensional Fe(III)-organodiphosphonate compound, [Fe(O3PCH2C6H4CH2PO3H)(H2O)], and an Expansion of the Harris Notation

AU - Lopez, Valerie

AU - Minichelli, Julian

AU - Case, Derek

AU - Ruhlandt, Karin

AU - Doyle, Robert P.

AU - Zubieta, Jon

PY - 2020/6/1

Y1 - 2020/6/1

N2 - The hydrothermal reaction of FeCl2·4H2O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C8H8P2O6H4), and triethylamine produced [Fe(o-C8H8P2O6H)(H2O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O6 octahedra linked through RPO3 tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.111213/2.11140] bonding mode, according to a modified Harris notation.

AB - The hydrothermal reaction of FeCl2·4H2O, 1,2-[phenelyenebis(methylene)]bis-phosphonic acid (o-C8H8P2O6H4), and triethylamine produced [Fe(o-C8H8P2O6H)(H2O)] as a yellow crystalline solid. The structure consists of two-dimensional networks of Fe(III)O6 octahedra linked through RPO3 tetrahedra. The xylyl groups project above and below these layers into the interlamellar domain. The iron coordination consists of five oxygen donors from five different phosphonate tetrahedra and an aqua ligand. The diphosphonate ligand adopts the [3.111213/2.11140] bonding mode, according to a modified Harris notation.

KW - Coordination polymer

KW - Iron(III)

KW - Organodiphosphonate

KW - Two-dimensional structure

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