Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(H O3P(CH2)4PO3H)} (Mo4FO12)2{O3P(CH2) 4PO3}]·4H2O, constructed from {Mo4FO

Stephanie Jones; Hongxue Liu; Wayne Ouellette; Katherine Schmidtke; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.inoche.2010.01.018

Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu₄(H₂O)₂(phenbisterpy)₂(H O₃P(CH₂)₄PO₃H)} (Mo₄FO₁₂)₂{O₃P(CH₂) ₄PO₃}]·4H₂O, constructed from {Mo₄FO

Stephanie Jones, Hongxue Liu, Wayne Ouellette, Katherine Schmidtke, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The hydrothermal reaction of Cu(CH₃CO₂)₂·H₂O, MoO₃, 1,4-bis(2,2′:6′,2″-terpyridin-4′-yl)benzene (phenbisterpy), 1,4-butylenediphosphonic acid and HF yielded green crystals of [{Cu₄(H₂O)₂(phenbisterpy)₂(H O₃P(CH₂)₄PO₃H)} (Mo₄FO₁₂)₂{O₃P(CH₂) ₄PO₃}]·4H₂O (1·4H₂O). The structure of 1·4H₂O is two-dimensional, with the network constructed from {Cu₄ (H₂ O)₂ (phenbisterpy)₂ (HO₃ P (CH₂)₄ PO₃ H)}_n ⁶ⁿ⁺ chains and [(Mo₄FO₁₂)₂{O₃P (CH₂)₄PO₃}]^6- clusters. The latter building block contains two tetranuclear clusters of face- and edge-sharing {MoO₅F} octahedra, linked through the diphosphonate ligand. The oxyfluoromolybdate cluster {Mo₄FO₁₂}^- is structurally distinct from the few examples of tetranuclear {Mo₄O₁₂F_x}^n- clusters, {Mo₄O₁₂F₂}^2- and {Mo₄O₁₂F₃}^3-.

Original language	English (US)
Pages (from-to)	491-494
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2010.01.018
State	Published - Apr 2010

Keywords

Bimetallic oxides
Copper molybdate
Organic-inorganic hybrid materials
Oxyfluoromolybdates

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2010.01.018

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Jones, S., Liu, H., Ouellette, W., Schmidtke, K., O'Connor, C. J., & Zubieta, J. (2010). Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu₄(H₂O)₂(phenbisterpy)₂(H O₃P(CH₂)₄PO₃H)} (Mo₄FO₁₂)₂{O₃P(CH₂) ₄PO₃}]·4H₂O, constructed from {Mo₄FO. Inorganic Chemistry Communications, 13(4), 491-494. https://doi.org/10.1016/j.inoche.2010.01.018

Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu₄(H₂O)₂(phenbisterpy)₂(H O₃P(CH₂)₄PO₃H)} (Mo₄FO₁₂)₂{O₃P(CH₂) ₄PO₃}]·4H₂O, constructed from {Mo₄FO. / Jones, Stephanie; Liu, Hongxue; Ouellette, Wayne et al.
In: Inorganic Chemistry Communications, Vol. 13, No. 4, 04.2010, p. 491-494.

Research output: Contribution to journal › Article › peer-review

Jones, S, Liu, H, Ouellette, W, Schmidtke, K, O'Connor, CJ & Zubieta, J 2010, 'Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu₄(H₂O)₂(phenbisterpy)₂(H O₃P(CH₂)₄PO₃H)} (Mo₄FO₁₂)₂{O₃P(CH₂) ₄PO₃}]·4H₂O, constructed from {Mo₄FO', Inorganic Chemistry Communications, vol. 13, no. 4, pp. 491-494. https://doi.org/10.1016/j.inoche.2010.01.018

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title = "Hydrothermal synthesis and structure of a two-dimensional bimetallic copper-molybdophosphonate, [{Cu4(H2O)2(phenbisterpy)2(H O3P(CH2)4PO3H)} (Mo4FO12)2{O3P(CH2) 4PO3}]·4H2O, constructed from {Mo4FO",

abstract = "The hydrothermal reaction of Cu(CH3CO2)2·H2O, MoO3, 1,4-bis(2,2′:6′,2″-terpyridin-4′-yl)benzene (phenbisterpy), 1,4-butylenediphosphonic acid and HF yielded green crystals of [{Cu4(H2O)2(phenbisterpy)2(H O3P(CH2)4PO3H)} (Mo4FO12)2{O3P(CH2) 4PO3}]·4H2O (1·4H2O). The structure of 1·4H2O is two-dimensional, with the network constructed from {Cu4 (H2 O)2 (phenbisterpy)2 (HO3 P (CH2)4 PO3 H)}n 6n+ chains and [(Mo4FO12)2{O3P (CH2)4PO3}]6- clusters. The latter building block contains two tetranuclear clusters of face- and edge-sharing {MoO5F} octahedra, linked through the diphosphonate ligand. The oxyfluoromolybdate cluster {Mo4FO12}- is structurally distinct from the few examples of tetranuclear {Mo4O12Fx}n- clusters, {Mo4O12F2}2- and {Mo4O12F3}3-.",

keywords = "Bimetallic oxides, Copper molybdate, Organic-inorganic hybrid materials, Oxyfluoromolybdates",

author = "Stephanie Jones and Hongxue Liu and Wayne Ouellette and Katherine Schmidtke and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by a Grant from the National Science Foundation ( CHE0907787 ). The magnetic studies were supported by a grant from the Louisiana Board of Regents through Contract Number LEQSF(2007-12)-ENH-PKSFI-PRS-04 . ",

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AU - Schmidtke, Katherine

AU - O'Connor, Charles J.

AU - Zubieta, Jon

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KW - Bimetallic oxides

KW - Copper molybdate

KW - Organic-inorganic hybrid materials

KW - Oxyfluoromolybdates

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