Hydrothermal synthesis and structural characterization of the two-dimensional networks [M(H2O)(bpy-dicarb)]•H2O (M = Fe, Co, Ni, Zn; bpy-dicarb = 2,2′-bipyridyl-4,4′-dicarboxylic acid)

Robert C. Finn; Jon Zubieta

doi:10.1016/S1293-2558(01)01215-8

Hydrothermal synthesis and structural characterization of the two-dimensional networks [M(H₂O)(bpy-dicarb)]•H₂O (M = Fe, Co, Ni, Zn; bpy-dicarb = 2,2′-bipyridyl-4,4′-dicarboxylic acid)

Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The hydrothermal reactions of the appropriate divalent metal salt 2,2′-bipyridyl-4,4′-dicarboxylic acid and H₂O in an approximate mole ratio of 2:1:2700 at 160 °C for 44 to 61 h yield [M(H₂O)(bpy-dicarb)]•H₂O[M = Fe(1•H₂O), Co(2•H₂O), Ni(3•H₂O), Zn(4•H₂O)]. The isomorphous series of compounds exhibit two-dimensional network structures, constructed from six coordinate M(II) sites linked through the bpy-dicarb ligands, each of which serves to bridge three metal sites. The water molecules of crystallization occupy cavities within the layers and are hydrogen bonded to the pendant carboxylate oxygen atom. Crystal data C₁₂H₁₀N₂O₆Fe (1•H₂O), monoclinic, P2₁/n: a = 11.9721(9) Å, b = 8.1977(6) Å, c = 12.696(1) Å, β = 98.492(1)°, V = 1232.4(2) Å³; C₁₂H₁₀N₂O₆Co (2•H₂O), monoclinic, P2₁/c: a = 11.9812(8) Å, b = 8.1698(6) Å, c = 12.6675(8) Å, β = 97.579(1)°, V = 1229.1(1) Å³; C₁₂H₁₀N₂O₆Ni (3•H₂O), monoclinic, P2₁/n: a = 11.9740(6) Å, b = 8.1866(4) Å, c = 12.5407(7) Å, β = 97.245(1)°, V = 1219.5(1) Å³; C₁₂H₁₀N₂O₆Zn (4•H₂O); monoclinic, P2₁/n: a = 12.0057(5) Å, b = 8.2370(3) Å, c = 12.6054(5) Å, β = 98.924(1)°, V = 1231.47(8) Å³.

Original language	English (US)
Pages (from-to)	83-86
Number of pages	4
Journal	Solid State Sciences
Volume	4
Issue number	1
DOIs	https://doi.org/10.1016/S1293-2558(01)01215-8
State	Published - 2002

Keywords

Hydrothermal synthesis
Network structures
Solid state coordination chemistry

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/S1293-2558(01)01215-8

Cite this

@article{fb237fd4a45343808b9d81e76c87f5c0,

title = "Hydrothermal synthesis and structural characterization of the two-dimensional networks [M(H2O)(bpy-dicarb)]•H2O (M = Fe, Co, Ni, Zn; bpy-dicarb = 2,2′-bipyridyl-4,4′-dicarboxylic acid)",

abstract = "The hydrothermal reactions of the appropriate divalent metal salt 2,2′-bipyridyl-4,4′-dicarboxylic acid and H2O in an approximate mole ratio of 2:1:2700 at 160 °C for 44 to 61 h yield [M(H2O)(bpy-dicarb)]•H2O[M = Fe(1•H2O), Co(2•H2O), Ni(3•H2O), Zn(4•H2O)]. The isomorphous series of compounds exhibit two-dimensional network structures, constructed from six coordinate M(II) sites linked through the bpy-dicarb ligands, each of which serves to bridge three metal sites. The water molecules of crystallization occupy cavities within the layers and are hydrogen bonded to the pendant carboxylate oxygen atom. Crystal data C12H10N2O6Fe (1•H2O), monoclinic, P21/n: a = 11.9721(9) {\AA}, b = 8.1977(6) {\AA}, c = 12.696(1) {\AA}, β = 98.492(1)°, V = 1232.4(2) {\AA}3; C12H10N2O6Co (2•H2O), monoclinic, P21/c: a = 11.9812(8) {\AA}, b = 8.1698(6) {\AA}, c = 12.6675(8) {\AA}, β = 97.579(1)°, V = 1229.1(1) {\AA}3; C12H10N2O6Ni (3•H2O), monoclinic, P21/n: a = 11.9740(6) {\AA}, b = 8.1866(4) {\AA}, c = 12.5407(7) {\AA}, β = 97.245(1)°, V = 1219.5(1) {\AA}3; C12H10N2O6Zn (4•H2O); monoclinic, P21/n: a = 12.0057(5) {\AA}, b = 8.2370(3) {\AA}, c = 12.6054(5) {\AA}, β = 98.924(1)°, V = 1231.47(8) {\AA}3.",

keywords = "Hydrothermal synthesis, Network structures, Solid state coordination chemistry",

author = "Finn, {Robert C.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation (CHE 9987471).",

year = "2002",

doi = "10.1016/S1293-2558(01)01215-8",

language = "English (US)",

volume = "4",

pages = "83--86",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "1",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of the two-dimensional networks [M(H2O)(bpy-dicarb)]•H2O (M = Fe, Co, Ni, Zn; bpy-dicarb = 2,2′-bipyridyl-4,4′-dicarboxylic acid)

AU - Finn, Robert C.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation (CHE 9987471).

PY - 2002

Y1 - 2002

N2 - The hydrothermal reactions of the appropriate divalent metal salt 2,2′-bipyridyl-4,4′-dicarboxylic acid and H2O in an approximate mole ratio of 2:1:2700 at 160 °C for 44 to 61 h yield [M(H2O)(bpy-dicarb)]•H2O[M = Fe(1•H2O), Co(2•H2O), Ni(3•H2O), Zn(4•H2O)]. The isomorphous series of compounds exhibit two-dimensional network structures, constructed from six coordinate M(II) sites linked through the bpy-dicarb ligands, each of which serves to bridge three metal sites. The water molecules of crystallization occupy cavities within the layers and are hydrogen bonded to the pendant carboxylate oxygen atom. Crystal data C12H10N2O6Fe (1•H2O), monoclinic, P21/n: a = 11.9721(9) Å, b = 8.1977(6) Å, c = 12.696(1) Å, β = 98.492(1)°, V = 1232.4(2) Å3; C12H10N2O6Co (2•H2O), monoclinic, P21/c: a = 11.9812(8) Å, b = 8.1698(6) Å, c = 12.6675(8) Å, β = 97.579(1)°, V = 1229.1(1) Å3; C12H10N2O6Ni (3•H2O), monoclinic, P21/n: a = 11.9740(6) Å, b = 8.1866(4) Å, c = 12.5407(7) Å, β = 97.245(1)°, V = 1219.5(1) Å3; C12H10N2O6Zn (4•H2O); monoclinic, P21/n: a = 12.0057(5) Å, b = 8.2370(3) Å, c = 12.6054(5) Å, β = 98.924(1)°, V = 1231.47(8) Å3.

AB - The hydrothermal reactions of the appropriate divalent metal salt 2,2′-bipyridyl-4,4′-dicarboxylic acid and H2O in an approximate mole ratio of 2:1:2700 at 160 °C for 44 to 61 h yield [M(H2O)(bpy-dicarb)]•H2O[M = Fe(1•H2O), Co(2•H2O), Ni(3•H2O), Zn(4•H2O)]. The isomorphous series of compounds exhibit two-dimensional network structures, constructed from six coordinate M(II) sites linked through the bpy-dicarb ligands, each of which serves to bridge three metal sites. The water molecules of crystallization occupy cavities within the layers and are hydrogen bonded to the pendant carboxylate oxygen atom. Crystal data C12H10N2O6Fe (1•H2O), monoclinic, P21/n: a = 11.9721(9) Å, b = 8.1977(6) Å, c = 12.696(1) Å, β = 98.492(1)°, V = 1232.4(2) Å3; C12H10N2O6Co (2•H2O), monoclinic, P21/c: a = 11.9812(8) Å, b = 8.1698(6) Å, c = 12.6675(8) Å, β = 97.579(1)°, V = 1229.1(1) Å3; C12H10N2O6Ni (3•H2O), monoclinic, P21/n: a = 11.9740(6) Å, b = 8.1866(4) Å, c = 12.5407(7) Å, β = 97.245(1)°, V = 1219.5(1) Å3; C12H10N2O6Zn (4•H2O); monoclinic, P21/n: a = 12.0057(5) Å, b = 8.2370(3) Å, c = 12.6054(5) Å, β = 98.924(1)°, V = 1231.47(8) Å3.

KW - Hydrothermal synthesis

KW - Network structures

KW - Solid state coordination chemistry

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U2 - 10.1016/S1293-2558(01)01215-8

DO - 10.1016/S1293-2558(01)01215-8

M3 - Article

AN - SCOPUS:0036180070

SN - 1293-2558

VL - 4

SP - 83

EP - 86

JO - Solid State Sciences

JF - Solid State Sciences

IS - 1

ER -