Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)-(VO2)(PO 4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]

Robert C. Finn; Jon Zubieta

doi:10.1039/b103994f

Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO₂)(PO₄)], [Zn(2,2′:6′,2″-terpyridine)-(VO₂)(PO ₄)], and [Zn(1,10-phenanthroline)(ZnVO)(PO₄)₂]

Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The hydrothermal reactions of zinc oxide, phosphoric acid, sodium orthovanadate, and the appropriate polyimine ligand at 200°C for 95, 68, and 42.5 h, respectively, have yielded three novel compounds, [Zn(bpy)(VO₂)(PO₄)] (1), [Zn(terpy)(VO₂)(PO₄)] (2), and [Zn(o-phen)(ZnVO)(PO₄)₂] (3). Compounds 1 and 2 are both one-dimensional chains with discreet {V₂P₂O₄} rings linked through zinc organoimine components. Compound 3 exhibits unusual {V₂P₄O₁₈} subunits which are bound through fully bridging zinc tetrahedra to form a two-dimensional sheet. The sheet is further surface decorated by {Zn(o-phen)}²⁺ moieties.

Original language	English (US)
Pages (from-to)	856-861
Number of pages	6
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	6
DOIs	https://doi.org/10.1039/b103994f
State	Published - Jan 1 2002

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Chemistry(all)

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Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates : [Zn(2,2′-bipyridine)(VO₂)(PO₄)], [Zn(2,2′:6′,2″-terpyridine)-(VO₂)(PO ₄)], and [Zn(1,10-phenanthroline)(ZnVO)(PO₄)₂]. / Finn, Robert C.; Zubieta, Jon.

In: Journal of the Chemical Society, Dalton Transactions, No. 6, 01.01.2002, p. 856-861.

Research output: Contribution to journal › Article › peer-review

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title = "Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)-(VO2)(PO 4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]",

abstract = "The hydrothermal reactions of zinc oxide, phosphoric acid, sodium orthovanadate, and the appropriate polyimine ligand at 200°C for 95, 68, and 42.5 h, respectively, have yielded three novel compounds, [Zn(bpy)(VO2)(PO4)] (1), [Zn(terpy)(VO2)(PO4)] (2), and [Zn(o-phen)(ZnVO)(PO4)2] (3). Compounds 1 and 2 are both one-dimensional chains with discreet {V2P2O4} rings linked through zinc organoimine components. Compound 3 exhibits unusual {V2P4O18} subunits which are bound through fully bridging zinc tetrahedra to form a two-dimensional sheet. The sheet is further surface decorated by {Zn(o-phen)}2+ moieties.",

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