Hydrothermal synthesis and structural characterization of [CU(en)2]2Cu7Cl11: A three-dimensional open-framework copper halide with occluded [Cu(en)2]2+ cations

Jeffrey R.D. DeBord; Ying Jie Lu; Christopher J. Warren; Robert C. Haushalter; Jon Zubieta

doi:10.1039/a702053h

Hydrothermal synthesis and structural characterization of [CU(en)₂]₂Cu₇Cl₁₁: A three-dimensional open-framework copper halide with occluded [Cu(en)₂]²⁺ cations

Jeffrey R.D. DeBord, Ying Jie Lu, Christopher J. Warren, Robert C. Haushalter, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl₂·H₂O and en, is built up from unusual chloride bridged Cu₄ tetramers connected by CuCl_3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en)₂]²⁺ cations.

Original language	English (US)
Pages (from-to)	1365-1366
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/a702053h
State	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl2·H2O and en, is built up from unusual chloride bridged Cu4 tetramers connected by CuCl3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en)2]2+ cations.",

author = "DeBord, {Jeffrey R.D.} and Lu, {Ying Jie} and Warren, {Christopher J.} and Haushalter, {Robert C.} and Jon Zubieta",

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doi = "10.1039/a702053h",

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T2 - A three-dimensional open-framework copper halide with occluded [Cu(en)2]2+ cations

AU - DeBord, Jeffrey R.D.

AU - Lu, Ying Jie

AU - Warren, Christopher J.

AU - Haushalter, Robert C.

AU - Zubieta, Jon

PY - 1997

Y1 - 1997

N2 - A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl2·H2O and en, is built up from unusual chloride bridged Cu4 tetramers connected by CuCl3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en)2]2+ cations.

AB - A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl2·H2O and en, is built up from unusual chloride bridged Cu4 tetramers connected by CuCl3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en)2]2+ cations.

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DO - 10.1039/a702053h

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Hydrothermal synthesis and structural characterization of [CU(en)₂]₂Cu₇Cl₁₁: A three-dimensional open-framework copper halide with occluded [Cu(en)₂]²⁺ cations

Abstract

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