Hydrothermal synthesis and structural characterization of bimetallic organic-inorganic hybrid materials: Copper vanadate-1,4-Carboxy-phenylphosphonate phases

Paul DeBurgomaster; Hongxue Liu; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.ica.2009.10.017

Hydrothermal synthesis and structural characterization of bimetallic organic-inorganic hybrid materials: Copper vanadate-1,4-Carboxy-phenylphosphonate phases

Paul DeBurgomaster, Hongxue Liu, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The hydrothermal reactions of V₂O₅, a copper(II) source, 1,4-carboxy-phenylphosphonic acid, a bidentate organonitrogen ligand and HF provided a series of bimetallic organic-inorganic hybrid materials. [Cu(bpy)VO₂(O₂CC₆H₄PO₃)] (1) is one-dimensional, while [Cu(bpa)VO(OH)(O₂CC₆H₄PO₃)] (2) and [Cu(phen)V₂O₄F(O₂CC₆H₄PO₃)] (3) are two-dimensional. In the absence of V₂O₅, a number of copper-organophosphonates were isolated. Compound 4 [Cu(phen)(H₂O)(O₂CC₆H₄PO₃H)] is one-dimensional while [Cu₃(bpy)₂(O₂CC₆H₄PO₃)₂] (5) is two-dimensional. Molecular structures were observed for [CuF(bpy)(H₂O)(HO₂CC₆H₄PO₃H)] (6) and [Cu(bpa)(O₂CC₆H₄PO₃H)]·3H₂O (7·3H₂O).

Original language	English (US)
Pages (from-to)	330-337
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	363
Issue number	2
DOIs	https://doi.org/10.1016/j.ica.2009.10.017
State	Published - Jan 15 2010

Keywords

Copper vanadates
Copper-organophosphonate
Organic-inorganic hybrid materials
Solid state coordination chemistry
Vanadium-organophosphonate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{c097855e893c40edb5f5139d71756047,

title = "Hydrothermal synthesis and structural characterization of bimetallic organic-inorganic hybrid materials: Copper vanadate-1,4-Carboxy-phenylphosphonate phases",

abstract = "The hydrothermal reactions of V2O5, a copper(II) source, 1,4-carboxy-phenylphosphonic acid, a bidentate organonitrogen ligand and HF provided a series of bimetallic organic-inorganic hybrid materials. [Cu(bpy)VO2(O2CC6H4PO3)] (1) is one-dimensional, while [Cu(bpa)VO(OH)(O2CC6H4PO3)] (2) and [Cu(phen)V2O4F(O2CC6H4PO3)] (3) are two-dimensional. In the absence of V2O5, a number of copper-organophosphonates were isolated. Compound 4 [Cu(phen)(H2O)(O2CC6H4PO3H)] is one-dimensional while [Cu3(bpy)2(O2CC6H4PO3)2] (5) is two-dimensional. Molecular structures were observed for [CuF(bpy)(H2O)(HO2CC6H4PO3H)] (6) and [Cu(bpa)(O2CC6H4PO3H)]·3H2O (7·3H2O).",

keywords = "Copper vanadates, Copper-organophosphonate, Organic-inorganic hybrid materials, Solid state coordination chemistry, Vanadium-organophosphonate",

author = "Paul DeBurgomaster and Hongxue Liu and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation , CHE-0907787 . The magnetic studies were made possible by a grant from the Defense Advanced Research Projects Agency (Grant MDA972-04-1-0029 ). ",

year = "2010",

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doi = "10.1016/j.ica.2009.10.017",

language = "English (US)",

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journal = "Inorganica Chimica Acta",

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T1 - Hydrothermal synthesis and structural characterization of bimetallic organic-inorganic hybrid materials

T2 - Copper vanadate-1,4-Carboxy-phenylphosphonate phases

AU - DeBurgomaster, Paul

AU - Liu, Hongxue

AU - O'Connor, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation , CHE-0907787 . The magnetic studies were made possible by a grant from the Defense Advanced Research Projects Agency (Grant MDA972-04-1-0029 ).

PY - 2010/1/15

Y1 - 2010/1/15

N2 - The hydrothermal reactions of V2O5, a copper(II) source, 1,4-carboxy-phenylphosphonic acid, a bidentate organonitrogen ligand and HF provided a series of bimetallic organic-inorganic hybrid materials. [Cu(bpy)VO2(O2CC6H4PO3)] (1) is one-dimensional, while [Cu(bpa)VO(OH)(O2CC6H4PO3)] (2) and [Cu(phen)V2O4F(O2CC6H4PO3)] (3) are two-dimensional. In the absence of V2O5, a number of copper-organophosphonates were isolated. Compound 4 [Cu(phen)(H2O)(O2CC6H4PO3H)] is one-dimensional while [Cu3(bpy)2(O2CC6H4PO3)2] (5) is two-dimensional. Molecular structures were observed for [CuF(bpy)(H2O)(HO2CC6H4PO3H)] (6) and [Cu(bpa)(O2CC6H4PO3H)]·3H2O (7·3H2O).

AB - The hydrothermal reactions of V2O5, a copper(II) source, 1,4-carboxy-phenylphosphonic acid, a bidentate organonitrogen ligand and HF provided a series of bimetallic organic-inorganic hybrid materials. [Cu(bpy)VO2(O2CC6H4PO3)] (1) is one-dimensional, while [Cu(bpa)VO(OH)(O2CC6H4PO3)] (2) and [Cu(phen)V2O4F(O2CC6H4PO3)] (3) are two-dimensional. In the absence of V2O5, a number of copper-organophosphonates were isolated. Compound 4 [Cu(phen)(H2O)(O2CC6H4PO3H)] is one-dimensional while [Cu3(bpy)2(O2CC6H4PO3)2] (5) is two-dimensional. Molecular structures were observed for [CuF(bpy)(H2O)(HO2CC6H4PO3H)] (6) and [Cu(bpa)(O2CC6H4PO3H)]·3H2O (7·3H2O).

KW - Copper vanadates

KW - Copper-organophosphonate

KW - Organic-inorganic hybrid materials

KW - Solid state coordination chemistry

KW - Vanadium-organophosphonate

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ER -

Hydrothermal synthesis and structural characterization of bimetallic organic-inorganic hybrid materials: Copper vanadate-1,4-Carboxy-phenylphosphonate phases

Abstract

Keywords

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